Benzyl­ammonium tetra­fluoro­borate 18-crown-6 clathrate

The reaction of benzyl­ammonium tetra­fluoro­borate and 18-crown-6 in a methano­lic solution yields the title compound, C(7)H(10)N(+)·BF(4) (−)·C(12)H(24)O(6)O6, which displays a supra­molecular structure. The –NH(3) (+) substituent of the benzyl­ammonium cation forms a 1:1 supra­molecular rotator–s...

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Detalles Bibliográficos
Autor principal: Zhao, Min Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007038/
https://www.ncbi.nlm.nih.gov/pubmed/21587849
http://dx.doi.org/10.1107/S1600536810021392
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author Zhao, Min Min
author_facet Zhao, Min Min
author_sort Zhao, Min Min
collection PubMed
description The reaction of benzyl­ammonium tetra­fluoro­borate and 18-crown-6 in a methano­lic solution yields the title compound, C(7)H(10)N(+)·BF(4) (−)·C(12)H(24)O(6)O6, which displays a supra­molecular structure. The –NH(3) (+) substituent of the benzyl­ammonium cation forms a 1:1 supra­molecular rotator–stator structure by N—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-30070382010-12-30 Benzyl­ammonium tetra­fluoro­borate 18-crown-6 clathrate Zhao, Min Min Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of benzyl­ammonium tetra­fluoro­borate and 18-crown-6 in a methano­lic solution yields the title compound, C(7)H(10)N(+)·BF(4) (−)·C(12)H(24)O(6)O6, which displays a supra­molecular structure. The –NH(3) (+) substituent of the benzyl­ammonium cation forms a 1:1 supra­molecular rotator–stator structure by N—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2010-06-09 /pmc/articles/PMC3007038/ /pubmed/21587849 http://dx.doi.org/10.1107/S1600536810021392 Text en © Min Min Zhao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Min Min
Benzyl­ammonium tetra­fluoro­borate 18-crown-6 clathrate
title Benzyl­ammonium tetra­fluoro­borate 18-crown-6 clathrate
title_full Benzyl­ammonium tetra­fluoro­borate 18-crown-6 clathrate
title_fullStr Benzyl­ammonium tetra­fluoro­borate 18-crown-6 clathrate
title_full_unstemmed Benzyl­ammonium tetra­fluoro­borate 18-crown-6 clathrate
title_short Benzyl­ammonium tetra­fluoro­borate 18-crown-6 clathrate
title_sort benzyl­ammonium tetra­fluoro­borate 18-crown-6 clathrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007038/
https://www.ncbi.nlm.nih.gov/pubmed/21587849
http://dx.doi.org/10.1107/S1600536810021392
work_keys_str_mv AT zhaominmin benzylammoniumtetrafluoroborate18crown6clathrate

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