Bis(ferrocene­carboxyl­ato-κO)bis­(2-pyridyl­methanol-κ(2) N,O)cobalt(II)

The title complex mol­ecule, [Fe(2)Co(C(5)H(5))(2)(C(6)H(4)O(2))(2)(C(6)H(7)NO)(2)], has a crystallographic imposed centre of symmetry. The Co(II) atom displays a distorted octa­hedral coordination geometry, provided by the O atoms of two monodentate ferrocene­carboxyl­ate anions and by the N and O...

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Detalles Bibliográficos
Autores principales: Yu, Youzhu, Guo, Yuhua, Wang, Daqi, Li, Dacheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007041/
https://www.ncbi.nlm.nih.gov/pubmed/21587689
http://dx.doi.org/10.1107/S1600536810020805
Descripción
Sumario:The title complex mol­ecule, [Fe(2)Co(C(5)H(5))(2)(C(6)H(4)O(2))(2)(C(6)H(7)NO)(2)], has a crystallographic imposed centre of symmetry. The Co(II) atom displays a distorted octa­hedral coordination geometry, provided by the O atoms of two monodentate ferrocene­carboxyl­ate anions and by the N and O atoms of two 2-pyridyl­methanol mol­ecule. The mol­ecular conformation is stabilized by intra­molecular C—H⋯O hydrogen bonds.

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