Bis(ferrocene­carboxyl­ato-κO)bis­(2-pyridyl­methanol-κ(2) N,O)cobalt(II)

The title complex mol­ecule, [Fe(2)Co(C(5)H(5))(2)(C(6)H(4)O(2))(2)(C(6)H(7)NO)(2)], has a crystallographic imposed centre of symmetry. The Co(II) atom displays a distorted octa­hedral coordination geometry, provided by the O atoms of two monodentate ferrocene­carboxyl­ate anions and by the N and O...

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Detalles Bibliográficos
Autores principales: Yu, Youzhu, Guo, Yuhua, Wang, Daqi, Li, Dacheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007041/
https://www.ncbi.nlm.nih.gov/pubmed/21587689
http://dx.doi.org/10.1107/S1600536810020805
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author Yu, Youzhu
Guo, Yuhua
Wang, Daqi
Li, Dacheng
author_facet Yu, Youzhu
Guo, Yuhua
Wang, Daqi
Li, Dacheng
author_sort Yu, Youzhu
collection PubMed
description The title complex mol­ecule, [Fe(2)Co(C(5)H(5))(2)(C(6)H(4)O(2))(2)(C(6)H(7)NO)(2)], has a crystallographic imposed centre of symmetry. The Co(II) atom displays a distorted octa­hedral coordination geometry, provided by the O atoms of two monodentate ferrocene­carboxyl­ate anions and by the N and O atoms of two 2-pyridyl­methanol mol­ecule. The mol­ecular conformation is stabilized by intra­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-30070412010-12-30 Bis(ferrocene­carboxyl­ato-κO)bis­(2-pyridyl­methanol-κ(2) N,O)cobalt(II) Yu, Youzhu Guo, Yuhua Wang, Daqi Li, Dacheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex mol­ecule, [Fe(2)Co(C(5)H(5))(2)(C(6)H(4)O(2))(2)(C(6)H(7)NO)(2)], has a crystallographic imposed centre of symmetry. The Co(II) atom displays a distorted octa­hedral coordination geometry, provided by the O atoms of two monodentate ferrocene­carboxyl­ate anions and by the N and O atoms of two 2-pyridyl­methanol mol­ecule. The mol­ecular conformation is stabilized by intra­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3007041/ /pubmed/21587689 http://dx.doi.org/10.1107/S1600536810020805 Text en © Yu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Youzhu
Guo, Yuhua
Wang, Daqi
Li, Dacheng
Bis(ferrocene­carboxyl­ato-κO)bis­(2-pyridyl­methanol-κ(2) N,O)cobalt(II)
title Bis(ferrocene­carboxyl­ato-κO)bis­(2-pyridyl­methanol-κ(2) N,O)cobalt(II)
title_full Bis(ferrocene­carboxyl­ato-κO)bis­(2-pyridyl­methanol-κ(2) N,O)cobalt(II)
title_fullStr Bis(ferrocene­carboxyl­ato-κO)bis­(2-pyridyl­methanol-κ(2) N,O)cobalt(II)
title_full_unstemmed Bis(ferrocene­carboxyl­ato-κO)bis­(2-pyridyl­methanol-κ(2) N,O)cobalt(II)
title_short Bis(ferrocene­carboxyl­ato-κO)bis­(2-pyridyl­methanol-κ(2) N,O)cobalt(II)
title_sort bis(ferrocene­carboxyl­ato-κo)bis­(2-pyridyl­methanol-κ(2) n,o)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007041/
https://www.ncbi.nlm.nih.gov/pubmed/21587689
http://dx.doi.org/10.1107/S1600536810020805
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AT guoyuhua bisferrocenecarboxylatokobis2pyridylmethanolk2nocobaltii
AT wangdaqi bisferrocenecarboxylatokobis2pyridylmethanolk2nocobaltii
AT lidacheng bisferrocenecarboxylatokobis2pyridylmethanolk2nocobaltii

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