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Dimethylammonium tetrachloridoferrate(III) 18-crown-6 clathrate
The reaction of dimethylamine hydrochloride, 18-crown-6 and ferric chloride in ethanol yields the title compound, (C(2)H(8)N)[FeCl(4)]·C(12)H(24)O(6), which exhibits an unusual supramolecular structure. The protonated dimethylamine contains one NH(2) (+) group, resulting in a 1:1 supramolecular...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007045/ https://www.ncbi.nlm.nih.gov/pubmed/21587672 http://dx.doi.org/10.1107/S1600536810020192 |
| _version_ | 1782194284609404928 |
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| author | Shi, Ping Ping Zhao, Min Min |
| author_facet | Shi, Ping Ping Zhao, Min Min |
| author_sort | Shi, Ping Ping |
| collection | PubMed |
| description | The reaction of dimethylamine hydrochloride, 18-crown-6 and ferric chloride in ethanol yields the title compound, (C(2)H(8)N)[FeCl(4)]·C(12)H(24)O(6), which exhibits an unusual supramolecular structure. The protonated dimethylamine contains one NH(2) (+) group, resulting in a 1:1 supramolecular rotator–stator structure (CH(3)—NH(2) (+)—CH(3))(18-crown-6), through N—H⋯O hydrogen-bonding interactions between the ammonium group of the cation and the O atoms of the crown ether. In the crystal, all three components lie on a common crystallographic mirror plane normal to [010]. |
| format | Text |
| id | pubmed-3007045 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30070452010-12-30 Dimethylammonium tetrachloridoferrate(III) 18-crown-6 clathrate Shi, Ping Ping Zhao, Min Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of dimethylamine hydrochloride, 18-crown-6 and ferric chloride in ethanol yields the title compound, (C(2)H(8)N)[FeCl(4)]·C(12)H(24)O(6), which exhibits an unusual supramolecular structure. The protonated dimethylamine contains one NH(2) (+) group, resulting in a 1:1 supramolecular rotator–stator structure (CH(3)—NH(2) (+)—CH(3))(18-crown-6), through N—H⋯O hydrogen-bonding interactions between the ammonium group of the cation and the O atoms of the crown ether. In the crystal, all three components lie on a common crystallographic mirror plane normal to [010]. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3007045/ /pubmed/21587672 http://dx.doi.org/10.1107/S1600536810020192 Text en © Shi and Zhao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shi, Ping Ping Zhao, Min Min Dimethylammonium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title | Dimethylammonium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title_full | Dimethylammonium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title_fullStr | Dimethylammonium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title_full_unstemmed | Dimethylammonium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title_short | Dimethylammonium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title_sort | dimethylammonium tetrachloridoferrate(iii) 18-crown-6 clathrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007045/ https://www.ncbi.nlm.nih.gov/pubmed/21587672 http://dx.doi.org/10.1107/S1600536810020192 |
| work_keys_str_mv | AT shipingping dimethylammoniumtetrachloridoferrateiii18crown6clathrate AT zhaominmin dimethylammoniumtetrachloridoferrateiii18crown6clathrate |