(R)-2-Benzyl-4-methyl­pentyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate

The relative configuration of the alcohol component in the title ester, C(27)H(32)O(3), has been assigned as (R) from the known configuration of (R)-(−)-2-meth­oxy-2-(1-naphth­yl)propionic acid [(R)-MαNP acid]. In the crystal structure, the C atom of the methyl group of the MαNP acid lies in the ext...

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Autores principales: Inoue, Yoshinori, Matsumoto, Takatoshi, Watanabe, Masataka, Katagiri, Hiroshi, Kumagai, Tsutomu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007046/
https://www.ncbi.nlm.nih.gov/pubmed/21587891
http://dx.doi.org/10.1107/S160053681002101X
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author Inoue, Yoshinori
Matsumoto, Takatoshi
Watanabe, Masataka
Katagiri, Hiroshi
Kumagai, Tsutomu
author_facet Inoue, Yoshinori
Matsumoto, Takatoshi
Watanabe, Masataka
Katagiri, Hiroshi
Kumagai, Tsutomu
author_sort Inoue, Yoshinori
collection PubMed
description The relative configuration of the alcohol component in the title ester, C(27)H(32)O(3), has been assigned as (R) from the known configuration of (R)-(−)-2-meth­oxy-2-(1-naphth­yl)propionic acid [(R)-MαNP acid]. In the crystal structure, the C atom of the methyl group of the MαNP acid lies in the extended plane of the naphthyl ring system [methyl C atom deviates from plane by 0.211 (2) Å; r.m.s. deviation of fitted atoms = 0.0187 Å] and a weak intra­molecular C—H⋯O hydrogen bond links the naphthyl ring system and the meth­oxy group. These structural properties are similar to those of most MαNP acid esters.
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spelling pubmed-30070462010-12-30 (R)-2-Benzyl-4-methyl­pentyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate Inoue, Yoshinori Matsumoto, Takatoshi Watanabe, Masataka Katagiri, Hiroshi Kumagai, Tsutomu Acta Crystallogr Sect E Struct Rep Online Organic Papers The relative configuration of the alcohol component in the title ester, C(27)H(32)O(3), has been assigned as (R) from the known configuration of (R)-(−)-2-meth­oxy-2-(1-naphth­yl)propionic acid [(R)-MαNP acid]. In the crystal structure, the C atom of the methyl group of the MαNP acid lies in the extended plane of the naphthyl ring system [methyl C atom deviates from plane by 0.211 (2) Å; r.m.s. deviation of fitted atoms = 0.0187 Å] and a weak intra­molecular C—H⋯O hydrogen bond links the naphthyl ring system and the meth­oxy group. These structural properties are similar to those of most MαNP acid esters. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3007046/ /pubmed/21587891 http://dx.doi.org/10.1107/S160053681002101X Text en © Inoue et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Inoue, Yoshinori
Matsumoto, Takatoshi
Watanabe, Masataka
Katagiri, Hiroshi
Kumagai, Tsutomu
(R)-2-Benzyl-4-methyl­pentyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title (R)-2-Benzyl-4-methyl­pentyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title_full (R)-2-Benzyl-4-methyl­pentyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title_fullStr (R)-2-Benzyl-4-methyl­pentyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title_full_unstemmed (R)-2-Benzyl-4-methyl­pentyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title_short (R)-2-Benzyl-4-methyl­pentyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title_sort (r)-2-benzyl-4-methyl­pentyl (r)-2-meth­oxy-2-(1-naphth­yl)propionate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007046/
https://www.ncbi.nlm.nih.gov/pubmed/21587891
http://dx.doi.org/10.1107/S160053681002101X
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AT kumagaitsutomu r2benzyl4methylpentylr2methoxy21naphthylpropionate

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