p-Tolyl 2-O-benzoyl-3-O-benzyl-4,6-O-benzyl­idene-1-thio-α-l-idopyran­oside

The title compound, C(34)H(32)O(6)S, is an ido-configured thio­glycoside building block for heparan sulfate fragments. It contains disordered tolyl and O-benzyl groups with occupancy ratios of 0.539 (13):0.461 (13) and 0.613 (13):0.387 (13), respectively, as determined from a weakly diffracting crys...

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Detalles Bibliográficos
Autores principales: Gainsford, Graeme J., Tyler, Peter C., Zubkova, Olga V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007053/
https://www.ncbi.nlm.nih.gov/pubmed/21587835
http://dx.doi.org/10.1107/S1600536810020970
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author Gainsford, Graeme J.
Tyler, Peter C.
Zubkova, Olga V.
author_facet Gainsford, Graeme J.
Tyler, Peter C.
Zubkova, Olga V.
author_sort Gainsford, Graeme J.
collection PubMed
description The title compound, C(34)H(32)O(6)S, is an ido-configured thio­glycoside building block for heparan sulfate fragments. It contains disordered tolyl and O-benzyl groups with occupancy ratios of 0.539 (13):0.461 (13) and 0.613 (13):0.387 (13), respectively, as determined from a weakly diffracting crystal. The fused rings adopt chair conformations with the mol­ecules packing into a three-dimensional network via C—H⋯O and three C—H⋯π inter­actions. The former inter­actions, occuring between mol­ecules related by a twofold axis, define an R (2) (2)(26) motif.
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spelling pubmed-30070532010-12-30 p-Tolyl 2-O-benzoyl-3-O-benzyl-4,6-O-benzyl­idene-1-thio-α-l-idopyran­oside Gainsford, Graeme J. Tyler, Peter C. Zubkova, Olga V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(34)H(32)O(6)S, is an ido-configured thio­glycoside building block for heparan sulfate fragments. It contains disordered tolyl and O-benzyl groups with occupancy ratios of 0.539 (13):0.461 (13) and 0.613 (13):0.387 (13), respectively, as determined from a weakly diffracting crystal. The fused rings adopt chair conformations with the mol­ecules packing into a three-dimensional network via C—H⋯O and three C—H⋯π inter­actions. The former inter­actions, occuring between mol­ecules related by a twofold axis, define an R (2) (2)(26) motif. International Union of Crystallography 2010-06-09 /pmc/articles/PMC3007053/ /pubmed/21587835 http://dx.doi.org/10.1107/S1600536810020970 Text en © Gainsford et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gainsford, Graeme J.
Tyler, Peter C.
Zubkova, Olga V.
p-Tolyl 2-O-benzoyl-3-O-benzyl-4,6-O-benzyl­idene-1-thio-α-l-idopyran­oside
title p-Tolyl 2-O-benzoyl-3-O-benzyl-4,6-O-benzyl­idene-1-thio-α-l-idopyran­oside
title_full p-Tolyl 2-O-benzoyl-3-O-benzyl-4,6-O-benzyl­idene-1-thio-α-l-idopyran­oside
title_fullStr p-Tolyl 2-O-benzoyl-3-O-benzyl-4,6-O-benzyl­idene-1-thio-α-l-idopyran­oside
title_full_unstemmed p-Tolyl 2-O-benzoyl-3-O-benzyl-4,6-O-benzyl­idene-1-thio-α-l-idopyran­oside
title_short p-Tolyl 2-O-benzoyl-3-O-benzyl-4,6-O-benzyl­idene-1-thio-α-l-idopyran­oside
title_sort p-tolyl 2-o-benzoyl-3-o-benzyl-4,6-o-benzyl­idene-1-thio-α-l-idopyran­oside
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007053/
https://www.ncbi.nlm.nih.gov/pubmed/21587835
http://dx.doi.org/10.1107/S1600536810020970
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