Poly[tetra­kis­(seleno­cyanato-κN)bis­(methanol-κO)tris­(μ-pyrimidine-κ(2) N:N′)dicobalt(II)]

In the title compound, [Co(2)(NCSe)(4)(C(4)H(4)N(2))(3)(CH(3)OH)(2)](n), the Co(II) ion is coordinated by three N-bonded pyrimidine ligands, two N-bonded seleno­cyanate anions and one O-bonded methanol mol­ecule in an octa­hedral coordination mode. The asymmetric unit consists of one Co(II) ion, one...

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Detalles Bibliográficos
Autores principales: Wriedt, Mario, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007058/
https://www.ncbi.nlm.nih.gov/pubmed/21587681
http://dx.doi.org/10.1107/S160053681002060X
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author Wriedt, Mario
Jess, Inke
Näther, Christian
author_facet Wriedt, Mario
Jess, Inke
Näther, Christian
author_sort Wriedt, Mario
collection PubMed
description In the title compound, [Co(2)(NCSe)(4)(C(4)H(4)N(2))(3)(CH(3)OH)(2)](n), the Co(II) ion is coordinated by three N-bonded pyrimidine ligands, two N-bonded seleno­cyanate anions and one O-bonded methanol mol­ecule in an octa­hedral coordination mode. The asymmetric unit consists of one Co(II) ion, one pyrimidine ligand, two seleno­cyanate anions and one methanol mol­ecule in general positions as well as one pyrimidine ligand located around a twofold rotation axis. In the crystal structure, the pyrimidine ligands bridge [Co(CNSe)(2)(CH(3)OH)] units into zigzag-like chains, which are further connected by pyrimidine ligands into layers parallel to (010).
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spelling pubmed-30070582010-12-30 Poly[tetra­kis­(seleno­cyanato-κN)bis­(methanol-κO)tris­(μ-pyrimidine-κ(2) N:N′)dicobalt(II)] Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(2)(NCSe)(4)(C(4)H(4)N(2))(3)(CH(3)OH)(2)](n), the Co(II) ion is coordinated by three N-bonded pyrimidine ligands, two N-bonded seleno­cyanate anions and one O-bonded methanol mol­ecule in an octa­hedral coordination mode. The asymmetric unit consists of one Co(II) ion, one pyrimidine ligand, two seleno­cyanate anions and one methanol mol­ecule in general positions as well as one pyrimidine ligand located around a twofold rotation axis. In the crystal structure, the pyrimidine ligands bridge [Co(CNSe)(2)(CH(3)OH)] units into zigzag-like chains, which are further connected by pyrimidine ligands into layers parallel to (010). International Union of Crystallography 2010-06-05 /pmc/articles/PMC3007058/ /pubmed/21587681 http://dx.doi.org/10.1107/S160053681002060X Text en © Wriedt et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wriedt, Mario
Jess, Inke
Näther, Christian
Poly[tetra­kis­(seleno­cyanato-κN)bis­(methanol-κO)tris­(μ-pyrimidine-κ(2) N:N′)dicobalt(II)]
title Poly[tetra­kis­(seleno­cyanato-κN)bis­(methanol-κO)tris­(μ-pyrimidine-κ(2) N:N′)dicobalt(II)]
title_full Poly[tetra­kis­(seleno­cyanato-κN)bis­(methanol-κO)tris­(μ-pyrimidine-κ(2) N:N′)dicobalt(II)]
title_fullStr Poly[tetra­kis­(seleno­cyanato-κN)bis­(methanol-κO)tris­(μ-pyrimidine-κ(2) N:N′)dicobalt(II)]
title_full_unstemmed Poly[tetra­kis­(seleno­cyanato-κN)bis­(methanol-κO)tris­(μ-pyrimidine-κ(2) N:N′)dicobalt(II)]
title_short Poly[tetra­kis­(seleno­cyanato-κN)bis­(methanol-κO)tris­(μ-pyrimidine-κ(2) N:N′)dicobalt(II)]
title_sort poly[tetra­kis­(seleno­cyanato-κn)bis­(methanol-κo)tris­(μ-pyrimidine-κ(2) n:n′)dicobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007058/
https://www.ncbi.nlm.nih.gov/pubmed/21587681
http://dx.doi.org/10.1107/S160053681002060X
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AT natherchristian polytetrakisselenocyanatoknbismethanolkotrismpyrimidinek2nndicobaltii

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