catena-Poly[[[(2-phenyl­acetato-κO)zinc(II)]bis­[μ-4,4′-(disulfanedi­yl)dipyridine-κ(2) N:N′]] monohydrate]

In the title compound, {[Zn(C(8)H(7)O(2))(2)(C(10)H(8)N(2)S(2))(2)]·H(2)O}(n), the Zn(II) atom is coordinated by four N atoms from four 4,4′-(disulfanedi­yl)dipyridine (bpds) ligands and two O atoms from two 2-phenyl­acetate anions in a distorted octa­hedral coordination geometry. The two bpds ligan...

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Detalles Bibliográficos
Autores principales: Zhang, Jie, Xu, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007060/
https://www.ncbi.nlm.nih.gov/pubmed/21587713
http://dx.doi.org/10.1107/S1600536810021331
Descripción
Sumario:In the title compound, {[Zn(C(8)H(7)O(2))(2)(C(10)H(8)N(2)S(2))(2)]·H(2)O}(n), the Zn(II) atom is coordinated by four N atoms from four 4,4′-(disulfanedi­yl)dipyridine (bpds) ligands and two O atoms from two 2-phenyl­acetate anions in a distorted octa­hedral coordination geometry. The two bpds ligands of the same axial chirality bridge Zn(II) atoms, generating repeated rhomboidal chains, which are linked by O—H⋯O hydrogen bonds into a ladder structure.

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