[(1S,2S)-2-(1-{[2-(2-Oxidobenzyl­idene­amino)­cyclo­hex­yl]imino}­eth­yl)phenolato-κ(4) O,N,N′,O′]copper(II)

In the title compound, [Cu(C(21)H(22)N(2)O(2))], the cyclo­hexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The Cu(II) ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The...

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Detalles Bibliográficos
Autores principales: Suleiman Gwaram, Nura, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007062/
https://www.ncbi.nlm.nih.gov/pubmed/21587731
http://dx.doi.org/10.1107/S1600536810022889
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author Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Suleiman Gwaram, Nura
collection PubMed
description In the title compound, [Cu(C(21)H(22)N(2)O(2))], the cyclo­hexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The Cu(II) ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings is 45.89 (9)°. The crystal structure is devoid of any classical hydrogen bonds. However, inter­molecular C—H⋯O inter­actions are present and stabilize the structure.
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spelling pubmed-30070622010-12-30 [(1S,2S)-2-(1-{[2-(2-Oxidobenzyl­idene­amino)­cyclo­hex­yl]imino}­eth­yl)phenolato-κ(4) O,N,N′,O′]copper(II) Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(21)H(22)N(2)O(2))], the cyclo­hexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The Cu(II) ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings is 45.89 (9)°. The crystal structure is devoid of any classical hydrogen bonds. However, inter­molecular C—H⋯O inter­actions are present and stabilize the structure. International Union of Crystallography 2010-06-18 /pmc/articles/PMC3007062/ /pubmed/21587731 http://dx.doi.org/10.1107/S1600536810022889 Text en © Suleiman Gwaram et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
[(1S,2S)-2-(1-{[2-(2-Oxidobenzyl­idene­amino)­cyclo­hex­yl]imino}­eth­yl)phenolato-κ(4) O,N,N′,O′]copper(II)
title [(1S,2S)-2-(1-{[2-(2-Oxidobenzyl­idene­amino)­cyclo­hex­yl]imino}­eth­yl)phenolato-κ(4) O,N,N′,O′]copper(II)
title_full [(1S,2S)-2-(1-{[2-(2-Oxidobenzyl­idene­amino)­cyclo­hex­yl]imino}­eth­yl)phenolato-κ(4) O,N,N′,O′]copper(II)
title_fullStr [(1S,2S)-2-(1-{[2-(2-Oxidobenzyl­idene­amino)­cyclo­hex­yl]imino}­eth­yl)phenolato-κ(4) O,N,N′,O′]copper(II)
title_full_unstemmed [(1S,2S)-2-(1-{[2-(2-Oxidobenzyl­idene­amino)­cyclo­hex­yl]imino}­eth­yl)phenolato-κ(4) O,N,N′,O′]copper(II)
title_short [(1S,2S)-2-(1-{[2-(2-Oxidobenzyl­idene­amino)­cyclo­hex­yl]imino}­eth­yl)phenolato-κ(4) O,N,N′,O′]copper(II)
title_sort [(1s,2s)-2-(1-{[2-(2-oxidobenzyl­idene­amino)­cyclo­hex­yl]imino}­eth­yl)phenolato-κ(4) o,n,n′,o′]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007062/
https://www.ncbi.nlm.nih.gov/pubmed/21587731
http://dx.doi.org/10.1107/S1600536810022889
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AT khaledihamid 1s2s2122oxidobenzylideneaminocyclohexyliminoethylphenolatok4onnocopperii
AT mohdalihapipah 1s2s2122oxidobenzylideneaminocyclohexyliminoethylphenolatok4onnocopperii

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