3,3-Bis[(4-chloro­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one

The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)°]. In the crystal, C—H⋯O...

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Detalles Bibliográficos
Autores principales: Zukerman-Schpector, Julio, De Simone, Carlos A., Olivato, Paulo R., Cerqueira, Carlos R., Santos, Jean M. M., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007065/
https://www.ncbi.nlm.nih.gov/pubmed/21588060
http://dx.doi.org/10.1107/S1600536810024347
Descripción
Sumario:The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)°]. In the crystal, C—H⋯O inter­actions link the mol­ecules into [010] supra­molecular chains with a helical topology. C—H⋯Cl and C—H⋯π inter­actions are also present.

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