3,3-Bis[(4-chloro­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one

The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)°]. In the crystal, C—H⋯O...

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Detalles Bibliográficos
Autores principales: Zukerman-Schpector, Julio, De Simone, Carlos A., Olivato, Paulo R., Cerqueira, Carlos R., Santos, Jean M. M., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007065/
https://www.ncbi.nlm.nih.gov/pubmed/21588060
http://dx.doi.org/10.1107/S1600536810024347
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author Zukerman-Schpector, Julio
De Simone, Carlos A.
Olivato, Paulo R.
Cerqueira, Carlos R.
Santos, Jean M. M.
Tiekink, Edward R. T.
author_facet Zukerman-Schpector, Julio
De Simone, Carlos A.
Olivato, Paulo R.
Cerqueira, Carlos R.
Santos, Jean M. M.
Tiekink, Edward R. T.
author_sort Zukerman-Schpector, Julio
collection PubMed
description The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)°]. In the crystal, C—H⋯O inter­actions link the mol­ecules into [010] supra­molecular chains with a helical topology. C—H⋯Cl and C—H⋯π inter­actions are also present.
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spelling pubmed-30070652010-12-30 3,3-Bis[(4-chloro­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one Zukerman-Schpector, Julio De Simone, Carlos A. Olivato, Paulo R. Cerqueira, Carlos R. Santos, Jean M. M. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)°]. In the crystal, C—H⋯O inter­actions link the mol­ecules into [010] supra­molecular chains with a helical topology. C—H⋯Cl and C—H⋯π inter­actions are also present. International Union of Crystallography 2010-06-30 /pmc/articles/PMC3007065/ /pubmed/21588060 http://dx.doi.org/10.1107/S1600536810024347 Text en © Zukerman-Schpector et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zukerman-Schpector, Julio
De Simone, Carlos A.
Olivato, Paulo R.
Cerqueira, Carlos R.
Santos, Jean M. M.
Tiekink, Edward R. T.
3,3-Bis[(4-chloro­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title 3,3-Bis[(4-chloro­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title_full 3,3-Bis[(4-chloro­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title_fullStr 3,3-Bis[(4-chloro­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title_full_unstemmed 3,3-Bis[(4-chloro­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title_short 3,3-Bis[(4-chloro­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
title_sort 3,3-bis[(4-chloro­phen­yl)sulfan­yl]-1-methyl­piperidin-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007065/
https://www.ncbi.nlm.nih.gov/pubmed/21588060
http://dx.doi.org/10.1107/S1600536810024347
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