Tetra­kis{μ(3)-2-[(2-hy­droxy­eth­yl)amino]­ethano­lato}tetra­kis­[chloridonickel(II)] methanol solvate

The complex mol­ecule of the title compound, [Ni(4)(C(4)H(10)NO(2))(4)Cl(4)]·CH(3)OH, consists of a cubane-like {Ni(4)O(4)} core in which each nickel(II) atom is six-coordinated in a distorted octa­hedral geometry by one N and four O atoms of three mono-deprotonated diethano­lamine ligands and by a...

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Detalles Bibliográficos
Autores principales: Yu, Youzhu, Guo, Yuhua, Lv, Lei, Li, Dacheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007071/
https://www.ncbi.nlm.nih.gov/pubmed/21587766
http://dx.doi.org/10.1107/S1600536810024384
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author Yu, Youzhu
Guo, Yuhua
Lv, Lei
Li, Dacheng
author_facet Yu, Youzhu
Guo, Yuhua
Lv, Lei
Li, Dacheng
author_sort Yu, Youzhu
collection PubMed
description The complex mol­ecule of the title compound, [Ni(4)(C(4)H(10)NO(2))(4)Cl(4)]·CH(3)OH, consists of a cubane-like {Ni(4)O(4)} core in which each nickel(II) atom is six-coordinated in a distorted octa­hedral geometry by one N and four O atoms of three mono-deprotonated diethano­lamine ligands and by a chloride anion. The mol­ecular conformation is stabilized by intra­molecular O—H⋯Cl bonds. In the crystal structure, complex mol­ecules and methanol solvent mol­ecules are linked into a three-dimensional network by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen-bonding inter­actions.
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spelling pubmed-30070712010-12-30 Tetra­kis{μ(3)-2-[(2-hy­droxy­eth­yl)amino]­ethano­lato}tetra­kis­[chloridonickel(II)] methanol solvate Yu, Youzhu Guo, Yuhua Lv, Lei Li, Dacheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex mol­ecule of the title compound, [Ni(4)(C(4)H(10)NO(2))(4)Cl(4)]·CH(3)OH, consists of a cubane-like {Ni(4)O(4)} core in which each nickel(II) atom is six-coordinated in a distorted octa­hedral geometry by one N and four O atoms of three mono-deprotonated diethano­lamine ligands and by a chloride anion. The mol­ecular conformation is stabilized by intra­molecular O—H⋯Cl bonds. In the crystal structure, complex mol­ecules and methanol solvent mol­ecules are linked into a three-dimensional network by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen-bonding inter­actions. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3007071/ /pubmed/21587766 http://dx.doi.org/10.1107/S1600536810024384 Text en © Yu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Youzhu
Guo, Yuhua
Lv, Lei
Li, Dacheng
Tetra­kis{μ(3)-2-[(2-hy­droxy­eth­yl)amino]­ethano­lato}tetra­kis­[chloridonickel(II)] methanol solvate
title Tetra­kis{μ(3)-2-[(2-hy­droxy­eth­yl)amino]­ethano­lato}tetra­kis­[chloridonickel(II)] methanol solvate
title_full Tetra­kis{μ(3)-2-[(2-hy­droxy­eth­yl)amino]­ethano­lato}tetra­kis­[chloridonickel(II)] methanol solvate
title_fullStr Tetra­kis{μ(3)-2-[(2-hy­droxy­eth­yl)amino]­ethano­lato}tetra­kis­[chloridonickel(II)] methanol solvate
title_full_unstemmed Tetra­kis{μ(3)-2-[(2-hy­droxy­eth­yl)amino]­ethano­lato}tetra­kis­[chloridonickel(II)] methanol solvate
title_short Tetra­kis{μ(3)-2-[(2-hy­droxy­eth­yl)amino]­ethano­lato}tetra­kis­[chloridonickel(II)] methanol solvate
title_sort tetra­kis{μ(3)-2-[(2-hy­droxy­eth­yl)amino]­ethano­lato}tetra­kis­[chloridonickel(ii)] methanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007071/
https://www.ncbi.nlm.nih.gov/pubmed/21587766
http://dx.doi.org/10.1107/S1600536810024384
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AT guoyuhua tetrakism322hydroxyethylaminoethanolatotetrakischloridonickeliimethanolsolvate
AT lvlei tetrakism322hydroxyethylaminoethanolatotetrakischloridonickeliimethanolsolvate
AT lidacheng tetrakism322hydroxyethylaminoethanolatotetrakischloridonickeliimethanolsolvate

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