Hexa­kis­(4-acetyl­pyridinium) octa­deca­chloridotetra­anti­monate(III)

The title compound, (C(7)H(8)NO)(6)[Sb(4)Cl(18)], contains centrosymmetric hexa­anions built up from four vertex-sharing alternating SbCl(5) square-based pyramids and highly distorted SbCl(6) octa­hedra when long (<3.2 Å) ‘secondary’ Sb—Cl inter­actions are taken into account. The inter-polyhedra...

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Detalles Bibliográficos
Autor principal: Fu, Xue-qun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007073/
https://www.ncbi.nlm.nih.gov/pubmed/21587677
http://dx.doi.org/10.1107/S160053681002057X
Descripción
Sumario:The title compound, (C(7)H(8)NO)(6)[Sb(4)Cl(18)], contains centrosymmetric hexa­anions built up from four vertex-sharing alternating SbCl(5) square-based pyramids and highly distorted SbCl(6) octa­hedra when long (<3.2 Å) ‘secondary’ Sb—Cl inter­actions are taken into account. The inter-polyhedral Sb—Cl bonds define a square-shape. In the crystal, the components are linked by N—H⋯Cl, C—H⋯Cl and C—H⋯O hydrogen bonds, generating a three-dimensional network.

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