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Hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(III)
The title compound, (C(7)H(8)NO)(6)[Sb(4)Cl(18)], contains centrosymmetric hexaanions built up from four vertex-sharing alternating SbCl(5) square-based pyramids and highly distorted SbCl(6) octahedra when long (<3.2 Å) ‘secondary’ Sb—Cl interactions are taken into account. The inter-polyhedra...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007073/ https://www.ncbi.nlm.nih.gov/pubmed/21587677 http://dx.doi.org/10.1107/S160053681002057X |
| _version_ | 1782194291427246080 |
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| author | Fu, Xue-qun |
| author_facet | Fu, Xue-qun |
| author_sort | Fu, Xue-qun |
| collection | PubMed |
| description | The title compound, (C(7)H(8)NO)(6)[Sb(4)Cl(18)], contains centrosymmetric hexaanions built up from four vertex-sharing alternating SbCl(5) square-based pyramids and highly distorted SbCl(6) octahedra when long (<3.2 Å) ‘secondary’ Sb—Cl interactions are taken into account. The inter-polyhedral Sb—Cl bonds define a square-shape. In the crystal, the components are linked by N—H⋯Cl, C—H⋯Cl and C—H⋯O hydrogen bonds, generating a three-dimensional network. |
| format | Text |
| id | pubmed-3007073 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30070732010-12-30 Hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(III) Fu, Xue-qun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(7)H(8)NO)(6)[Sb(4)Cl(18)], contains centrosymmetric hexaanions built up from four vertex-sharing alternating SbCl(5) square-based pyramids and highly distorted SbCl(6) octahedra when long (<3.2 Å) ‘secondary’ Sb—Cl interactions are taken into account. The inter-polyhedral Sb—Cl bonds define a square-shape. In the crystal, the components are linked by N—H⋯Cl, C—H⋯Cl and C—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3007073/ /pubmed/21587677 http://dx.doi.org/10.1107/S160053681002057X Text en © Xue-qun Fu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fu, Xue-qun Hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(III) |
| title | Hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(III) |
| title_full | Hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(III) |
| title_fullStr | Hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(III) |
| title_full_unstemmed | Hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(III) |
| title_short | Hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(III) |
| title_sort | hexakis(4-acetylpyridinium) octadecachloridotetraantimonate(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007073/ https://www.ncbi.nlm.nih.gov/pubmed/21587677 http://dx.doi.org/10.1107/S160053681002057X |
| work_keys_str_mv | AT fuxuequn hexakis4acetylpyridiniumoctadecachloridotetraantimonateiii |