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Bis{2-[(2-benzoyl­hydrazin-1-yl­idene)meth­yl]-6-meth­oxy­phenolato}iron(III) chloride monohydrate

In the title mononuclear iron(III) complex, [Fe(C(15)H(13)N(2)O(3))(2)]Cl·H(2)O, the Fe(III) atom has a distorted octa­hedral geometry and is six-coordinated by four O atoms and two N atoms from two ligands. In the crystal structure, the complex cations, Cl(−) anions and water mol­ecules are connect...

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Detalles Bibliográficos
Autores principales: Zou, Li-Fei, Ma, Yu-Qin, Yu, Gui-Miao, Gan, Feng-Jiao, Li, Yun-Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007077/
https://www.ncbi.nlm.nih.gov/pubmed/21587741
http://dx.doi.org/10.1107/S1600536810023226
Descripción
Sumario:In the title mononuclear iron(III) complex, [Fe(C(15)H(13)N(2)O(3))(2)]Cl·H(2)O, the Fe(III) atom has a distorted octa­hedral geometry and is six-coordinated by four O atoms and two N atoms from two ligands. In the crystal structure, the complex cations, Cl(−) anions and water mol­ecules are connected into a chain along [100] through N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds. Two adjacent chains are linked by O—H⋯O hydrogen bonds.