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Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate
In the title mononuclear iron(III) complex, [Fe(C(15)H(13)N(2)O(3))(2)]Cl·H(2)O, the Fe(III) atom has a distorted octahedral geometry and is six-coordinated by four O atoms and two N atoms from two ligands. In the crystal structure, the complex cations, Cl(−) anions and water molecules are connect...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007077/ https://www.ncbi.nlm.nih.gov/pubmed/21587741 http://dx.doi.org/10.1107/S1600536810023226 |
| _version_ | 1782194292427587584 |
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| author | Zou, Li-Fei Ma, Yu-Qin Yu, Gui-Miao Gan, Feng-Jiao Li, Yun-Hui |
| author_facet | Zou, Li-Fei Ma, Yu-Qin Yu, Gui-Miao Gan, Feng-Jiao Li, Yun-Hui |
| author_sort | Zou, Li-Fei |
| collection | PubMed |
| description | In the title mononuclear iron(III) complex, [Fe(C(15)H(13)N(2)O(3))(2)]Cl·H(2)O, the Fe(III) atom has a distorted octahedral geometry and is six-coordinated by four O atoms and two N atoms from two ligands. In the crystal structure, the complex cations, Cl(−) anions and water molecules are connected into a chain along [100] through N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds. Two adjacent chains are linked by O—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-3007077 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30070772010-12-30 Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate Zou, Li-Fei Ma, Yu-Qin Yu, Gui-Miao Gan, Feng-Jiao Li, Yun-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear iron(III) complex, [Fe(C(15)H(13)N(2)O(3))(2)]Cl·H(2)O, the Fe(III) atom has a distorted octahedral geometry and is six-coordinated by four O atoms and two N atoms from two ligands. In the crystal structure, the complex cations, Cl(−) anions and water molecules are connected into a chain along [100] through N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds. Two adjacent chains are linked by O—H⋯O hydrogen bonds. International Union of Crystallography 2010-06-23 /pmc/articles/PMC3007077/ /pubmed/21587741 http://dx.doi.org/10.1107/S1600536810023226 Text en © Zou et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zou, Li-Fei Ma, Yu-Qin Yu, Gui-Miao Gan, Feng-Jiao Li, Yun-Hui Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate |
| title | Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate |
| title_full | Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate |
| title_fullStr | Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate |
| title_full_unstemmed | Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate |
| title_short | Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate |
| title_sort | bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(iii) chloride monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007077/ https://www.ncbi.nlm.nih.gov/pubmed/21587741 http://dx.doi.org/10.1107/S1600536810023226 |
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