(E)-N′-(4-Nitro­benzyl­idene)-4-(8-quinol­yloxy)butano­hydrazide

In the title compound, C(20)H(18)N(4)O(4), conformation along the bond sequence linking the benzene and quinoline rings, which have a mean inter­planar dihedral angle of 2.7 (5)°, is trans–(+)gauche–trans–trans–(−)gauche–trans–trans. In the crystal structure, a pair of inter­molecular N—H⋯O hydrogen...

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Detalles Bibliográficos
Autores principales: XiaHou, Guo-Lun, Ding, Ye-Chun, Fan, Xiao-Na
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007085/
https://www.ncbi.nlm.nih.gov/pubmed/21587772
http://dx.doi.org/10.1107/S1600536810020039
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author XiaHou, Guo-Lun
Ding, Ye-Chun
Fan, Xiao-Na
author_facet XiaHou, Guo-Lun
Ding, Ye-Chun
Fan, Xiao-Na
author_sort XiaHou, Guo-Lun
collection PubMed
description In the title compound, C(20)H(18)N(4)O(4), conformation along the bond sequence linking the benzene and quinoline rings, which have a mean inter­planar dihedral angle of 2.7 (5)°, is trans–(+)gauche–trans–trans–(−)gauche–trans–trans. In the crystal structure, a pair of inter­molecular N—H⋯O hydrogen bonds links the mol­ecules into centrosymmetric cyclic R (2) (2)(8) dimers, which are aggregated via π–π inter­actions into parallel sheets [quinoline–benzene ring centroid separation = 3.6173 (16)–3.6511 (16) Å]. The sheets are further connected through weak C—H⋯O inter­actions, giving a supra­molecular two-dimensional network.
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spelling pubmed-30070852010-12-30 (E)-N′-(4-Nitro­benzyl­idene)-4-(8-quinol­yloxy)butano­hydrazide XiaHou, Guo-Lun Ding, Ye-Chun Fan, Xiao-Na Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(18)N(4)O(4), conformation along the bond sequence linking the benzene and quinoline rings, which have a mean inter­planar dihedral angle of 2.7 (5)°, is trans–(+)gauche–trans–trans–(−)gauche–trans–trans. In the crystal structure, a pair of inter­molecular N—H⋯O hydrogen bonds links the mol­ecules into centrosymmetric cyclic R (2) (2)(8) dimers, which are aggregated via π–π inter­actions into parallel sheets [quinoline–benzene ring centroid separation = 3.6173 (16)–3.6511 (16) Å]. The sheets are further connected through weak C—H⋯O inter­actions, giving a supra­molecular two-dimensional network. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3007085/ /pubmed/21587772 http://dx.doi.org/10.1107/S1600536810020039 Text en © XiaHou et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
XiaHou, Guo-Lun
Ding, Ye-Chun
Fan, Xiao-Na
(E)-N′-(4-Nitro­benzyl­idene)-4-(8-quinol­yloxy)butano­hydrazide
title (E)-N′-(4-Nitro­benzyl­idene)-4-(8-quinol­yloxy)butano­hydrazide
title_full (E)-N′-(4-Nitro­benzyl­idene)-4-(8-quinol­yloxy)butano­hydrazide
title_fullStr (E)-N′-(4-Nitro­benzyl­idene)-4-(8-quinol­yloxy)butano­hydrazide
title_full_unstemmed (E)-N′-(4-Nitro­benzyl­idene)-4-(8-quinol­yloxy)butano­hydrazide
title_short (E)-N′-(4-Nitro­benzyl­idene)-4-(8-quinol­yloxy)butano­hydrazide
title_sort (e)-n′-(4-nitro­benzyl­idene)-4-(8-quinol­yloxy)butano­hydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007085/
https://www.ncbi.nlm.nih.gov/pubmed/21587772
http://dx.doi.org/10.1107/S1600536810020039
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AT fanxiaona en4nitrobenzylidene48quinolyloxybutanohydrazide

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