4-(1H-Benzimidazol-2-ylmeth­oxy)-3-eth­oxy­benzaldehyde trihydrate

In the title compound, C(17)H(16)N(2)O(3)·3H(2)O, the dihedral angle between the mean planes of the benzene and benzimidazole systems is 26.2 (3)°. These groups are slightly twisted around the eth­oxy­methane unit [C—C—O—C torsion angle = 177.64 (15)°]. The crystal packing is stabilized by N—H⋯O, O—...

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Autores principales: Jasinski, Jerry P., Braley, Adam N., Samshuddin, S., Narayana, B., Yathirajan, H. S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007197/
https://www.ncbi.nlm.nih.gov/pubmed/21588359
http://dx.doi.org/10.1107/S1600536810027455
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author Jasinski, Jerry P.
Braley, Adam N.
Samshuddin, S.
Narayana, B.
Yathirajan, H. S.
author_facet Jasinski, Jerry P.
Braley, Adam N.
Samshuddin, S.
Narayana, B.
Yathirajan, H. S.
author_sort Jasinski, Jerry P.
collection PubMed
description In the title compound, C(17)H(16)N(2)O(3)·3H(2)O, the dihedral angle between the mean planes of the benzene and benzimidazole systems is 26.2 (3)°. These groups are slightly twisted around the eth­oxy­methane unit [C—C—O—C torsion angle = 177.64 (15)°]. The crystal packing is stabilized by N—H⋯O, O—H⋯N and O—H⋯O hydrogen-bond inter­actions involving the water mol­ecules. Weak π–π stacking inter­actions [centroid–centroid distances = 3.7943 (7), 3.6919 (13) and 3.7533 (14) Å] contribute to the mol­ecular stability.
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spelling pubmed-30071972010-12-30 4-(1H-Benzimidazol-2-ylmeth­oxy)-3-eth­oxy­benzaldehyde trihydrate Jasinski, Jerry P. Braley, Adam N. Samshuddin, S. Narayana, B. Yathirajan, H. S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(16)N(2)O(3)·3H(2)O, the dihedral angle between the mean planes of the benzene and benzimidazole systems is 26.2 (3)°. These groups are slightly twisted around the eth­oxy­methane unit [C—C—O—C torsion angle = 177.64 (15)°]. The crystal packing is stabilized by N—H⋯O, O—H⋯N and O—H⋯O hydrogen-bond inter­actions involving the water mol­ecules. Weak π–π stacking inter­actions [centroid–centroid distances = 3.7943 (7), 3.6919 (13) and 3.7533 (14) Å] contribute to the mol­ecular stability. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007197/ /pubmed/21588359 http://dx.doi.org/10.1107/S1600536810027455 Text en © Jasinski et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jasinski, Jerry P.
Braley, Adam N.
Samshuddin, S.
Narayana, B.
Yathirajan, H. S.
4-(1H-Benzimidazol-2-ylmeth­oxy)-3-eth­oxy­benzaldehyde trihydrate
title 4-(1H-Benzimidazol-2-ylmeth­oxy)-3-eth­oxy­benzaldehyde trihydrate
title_full 4-(1H-Benzimidazol-2-ylmeth­oxy)-3-eth­oxy­benzaldehyde trihydrate
title_fullStr 4-(1H-Benzimidazol-2-ylmeth­oxy)-3-eth­oxy­benzaldehyde trihydrate
title_full_unstemmed 4-(1H-Benzimidazol-2-ylmeth­oxy)-3-eth­oxy­benzaldehyde trihydrate
title_short 4-(1H-Benzimidazol-2-ylmeth­oxy)-3-eth­oxy­benzaldehyde trihydrate
title_sort 4-(1h-benzimidazol-2-ylmeth­oxy)-3-eth­oxy­benzaldehyde trihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007197/
https://www.ncbi.nlm.nih.gov/pubmed/21588359
http://dx.doi.org/10.1107/S1600536810027455
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AT narayanab 41hbenzimidazol2ylmethoxy3ethoxybenzaldehydetrihydrate
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