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{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]propane-1,2-diamine}­bis(thio­cyanato-κN)­nickel(II)

In the title complex, [Ni(NCS)(2)(C(17)H(20)N(4))], the Ni(2+) ion (site symmetry 2) is coordinated by the N,N,N,N-tetra­dentate Schiff base ligand and two thio­cyanate ligands, forming a distorted NiN(6) octa­hedral geometry, with the thio­cyanate N atoms in a trans orientation. The pendant methyl...

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Detalles Bibliográficos
Autor principal: Wang, Ning
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007198/
https://www.ncbi.nlm.nih.gov/pubmed/21588107
http://dx.doi.org/10.1107/S1600536810029454
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author Wang, Ning
author_facet Wang, Ning
author_sort Wang, Ning
collection PubMed
description In the title complex, [Ni(NCS)(2)(C(17)H(20)N(4))], the Ni(2+) ion (site symmetry 2) is coordinated by the N,N,N,N-tetra­dentate Schiff base ligand and two thio­cyanate ligands, forming a distorted NiN(6) octa­hedral geometry, with the thio­cyanate N atoms in a trans orientation. The pendant methyl group of the central propane-1,2-diamine fragment of the ligand is statistically disordered over two sets of positions. In the crystal, weak aromatic π–π stacking between pyridine rings [centroid–centroid separation = 3.7081 (17) Å] may help to establish the packing.
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spelling pubmed-30071982010-12-30 {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]propane-1,2-diamine}­bis(thio­cyanato-κN)­nickel(II) Wang, Ning Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(NCS)(2)(C(17)H(20)N(4))], the Ni(2+) ion (site symmetry 2) is coordinated by the N,N,N,N-tetra­dentate Schiff base ligand and two thio­cyanate ligands, forming a distorted NiN(6) octa­hedral geometry, with the thio­cyanate N atoms in a trans orientation. The pendant methyl group of the central propane-1,2-diamine fragment of the ligand is statistically disordered over two sets of positions. In the crystal, weak aromatic π–π stacking between pyridine rings [centroid–centroid separation = 3.7081 (17) Å] may help to establish the packing. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007198/ /pubmed/21588107 http://dx.doi.org/10.1107/S1600536810029454 Text en © Ning Wang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ning
{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]propane-1,2-diamine}­bis(thio­cyanato-κN)­nickel(II)
title {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]propane-1,2-diamine}­bis(thio­cyanato-κN)­nickel(II)
title_full {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]propane-1,2-diamine}­bis(thio­cyanato-κN)­nickel(II)
title_fullStr {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]propane-1,2-diamine}­bis(thio­cyanato-κN)­nickel(II)
title_full_unstemmed {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]propane-1,2-diamine}­bis(thio­cyanato-κN)­nickel(II)
title_short {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]propane-1,2-diamine}­bis(thio­cyanato-κN)­nickel(II)
title_sort {n,n′-bis[1-(2-pyrid­yl)ethyl­idene]propane-1,2-diamine}­bis(thio­cyanato-κn)­nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007198/
https://www.ncbi.nlm.nih.gov/pubmed/21588107
http://dx.doi.org/10.1107/S1600536810029454
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