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{N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine}bis(thiocyanato-κN)nickel(II)
In the title complex, [Ni(NCS)(2)(C(17)H(20)N(4))], the Ni(2+) ion (site symmetry 2) is coordinated by the N,N,N,N-tetradentate Schiff base ligand and two thiocyanate ligands, forming a distorted NiN(6) octahedral geometry, with the thiocyanate N atoms in a trans orientation. The pendant methyl...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007198/ https://www.ncbi.nlm.nih.gov/pubmed/21588107 http://dx.doi.org/10.1107/S1600536810029454 |
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author | Wang, Ning |
author_facet | Wang, Ning |
author_sort | Wang, Ning |
collection | PubMed |
description | In the title complex, [Ni(NCS)(2)(C(17)H(20)N(4))], the Ni(2+) ion (site symmetry 2) is coordinated by the N,N,N,N-tetradentate Schiff base ligand and two thiocyanate ligands, forming a distorted NiN(6) octahedral geometry, with the thiocyanate N atoms in a trans orientation. The pendant methyl group of the central propane-1,2-diamine fragment of the ligand is statistically disordered over two sets of positions. In the crystal, weak aromatic π–π stacking between pyridine rings [centroid–centroid separation = 3.7081 (17) Å] may help to establish the packing. |
format | Text |
id | pubmed-3007198 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30071982010-12-30 {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine}bis(thiocyanato-κN)nickel(II) Wang, Ning Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(NCS)(2)(C(17)H(20)N(4))], the Ni(2+) ion (site symmetry 2) is coordinated by the N,N,N,N-tetradentate Schiff base ligand and two thiocyanate ligands, forming a distorted NiN(6) octahedral geometry, with the thiocyanate N atoms in a trans orientation. The pendant methyl group of the central propane-1,2-diamine fragment of the ligand is statistically disordered over two sets of positions. In the crystal, weak aromatic π–π stacking between pyridine rings [centroid–centroid separation = 3.7081 (17) Å] may help to establish the packing. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007198/ /pubmed/21588107 http://dx.doi.org/10.1107/S1600536810029454 Text en © Ning Wang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Ning {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine}bis(thiocyanato-κN)nickel(II) |
title | {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine}bis(thiocyanato-κN)nickel(II) |
title_full | {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine}bis(thiocyanato-κN)nickel(II) |
title_fullStr | {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine}bis(thiocyanato-κN)nickel(II) |
title_full_unstemmed | {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine}bis(thiocyanato-κN)nickel(II) |
title_short | {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine}bis(thiocyanato-κN)nickel(II) |
title_sort | {n,n′-bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine}bis(thiocyanato-κn)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007198/ https://www.ncbi.nlm.nih.gov/pubmed/21588107 http://dx.doi.org/10.1107/S1600536810029454 |
work_keys_str_mv | AT wangning nnbis12pyridylethylidenepropane12diaminebisthiocyanatoknnickelii |