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2-(4-Bromophenyl)-5-fluoro-3-phenylsulfinyl-1-benzofuran
In the title compound, C(20)H(12)BrFO(2)S, the O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment; the phenyl ring is nearly perpendicular to this plane [dihedral angle = 86.98 (6)°]. The 4-bromophenyl ring is rotated sl...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007207/ https://www.ncbi.nlm.nih.gov/pubmed/21588453 http://dx.doi.org/10.1107/S1600536810029958 |
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author | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_facet | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_sort | Choi, Hong Dae |
collection | PubMed |
description | In the title compound, C(20)H(12)BrFO(2)S, the O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment; the phenyl ring is nearly perpendicular to this plane [dihedral angle = 86.98 (6)°]. The 4-bromophenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 1.56 (8)°. The crystal structure features aromatic π–π interactions between the furan and phenyl rings of neighbouring molecules [centroid–centroid distance = 3.506 (3) Å], and an intermolecular C—H⋯π interaction. The crystal structure also exhibits a short intermolecular S⋯S contact [3.2635 (8) Å]. |
format | Text |
id | pubmed-3007207 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072072010-12-30 2-(4-Bromophenyl)-5-fluoro-3-phenylsulfinyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(12)BrFO(2)S, the O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment; the phenyl ring is nearly perpendicular to this plane [dihedral angle = 86.98 (6)°]. The 4-bromophenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 1.56 (8)°. The crystal structure features aromatic π–π interactions between the furan and phenyl rings of neighbouring molecules [centroid–centroid distance = 3.506 (3) Å], and an intermolecular C—H⋯π interaction. The crystal structure also exhibits a short intermolecular S⋯S contact [3.2635 (8) Å]. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007207/ /pubmed/21588453 http://dx.doi.org/10.1107/S1600536810029958 Text en © Choi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk 2-(4-Bromophenyl)-5-fluoro-3-phenylsulfinyl-1-benzofuran |
title | 2-(4-Bromophenyl)-5-fluoro-3-phenylsulfinyl-1-benzofuran |
title_full | 2-(4-Bromophenyl)-5-fluoro-3-phenylsulfinyl-1-benzofuran |
title_fullStr | 2-(4-Bromophenyl)-5-fluoro-3-phenylsulfinyl-1-benzofuran |
title_full_unstemmed | 2-(4-Bromophenyl)-5-fluoro-3-phenylsulfinyl-1-benzofuran |
title_short | 2-(4-Bromophenyl)-5-fluoro-3-phenylsulfinyl-1-benzofuran |
title_sort | 2-(4-bromophenyl)-5-fluoro-3-phenylsulfinyl-1-benzofuran |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007207/ https://www.ncbi.nlm.nih.gov/pubmed/21588453 http://dx.doi.org/10.1107/S1600536810029958 |
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