Bis(μ-quinoline-2-carboxyl­ato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)(methanol-κO)lead(II)]

The dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(CH(3)OH)(2)], lies across an inversion center. The methanol-coordinated Pb(II) atom is chelated by the acetate anion as well as by the quinoline-2-carboxyl­ate anion. One O atom of the quinoline-2-carboxyl­ate anion bridges two sym...

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Autores principales: Mohammadnezhad, Gholamhossein, Ghanbarpour, Ali Reza, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007209/
https://www.ncbi.nlm.nih.gov/pubmed/21588188
http://dx.doi.org/10.1107/S1600536810027777
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author Mohammadnezhad, Gholamhossein
Ghanbarpour, Ali Reza
Amini, Mostafa M.
Ng, Seik Weng
author_facet Mohammadnezhad, Gholamhossein
Ghanbarpour, Ali Reza
Amini, Mostafa M.
Ng, Seik Weng
author_sort Mohammadnezhad, Gholamhossein
collection PubMed
description The dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(CH(3)OH)(2)], lies across an inversion center. The methanol-coordinated Pb(II) atom is chelated by the acetate anion as well as by the quinoline-2-carboxyl­ate anion. One O atom of the quinoline-2-carboxyl­ate anion bridges two symmetry-related Pb(II) atoms, forming the dinuclear compound. Aside from the six atoms connected to the Pb(II) atom by regular coordination bonds, the structure features a long Pb⋯O inter­action [3.145 (3) Å] that gives rise to a distorted Ψ-square-anti­prismatic geometry at the metal center. The H atom of the methanol is hydrogen bonded to an O atom of the acetate.
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spelling pubmed-30072092010-12-30 Bis(μ-quinoline-2-carboxyl­ato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)(methanol-κO)lead(II)] Mohammadnezhad, Gholamhossein Ghanbarpour, Ali Reza Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(CH(3)OH)(2)], lies across an inversion center. The methanol-coordinated Pb(II) atom is chelated by the acetate anion as well as by the quinoline-2-carboxyl­ate anion. One O atom of the quinoline-2-carboxyl­ate anion bridges two symmetry-related Pb(II) atoms, forming the dinuclear compound. Aside from the six atoms connected to the Pb(II) atom by regular coordination bonds, the structure features a long Pb⋯O inter­action [3.145 (3) Å] that gives rise to a distorted Ψ-square-anti­prismatic geometry at the metal center. The H atom of the methanol is hydrogen bonded to an O atom of the acetate. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007209/ /pubmed/21588188 http://dx.doi.org/10.1107/S1600536810027777 Text en © Mohammadnezhad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mohammadnezhad, Gholamhossein
Ghanbarpour, Ali Reza
Amini, Mostafa M.
Ng, Seik Weng
Bis(μ-quinoline-2-carboxyl­ato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)(methanol-κO)lead(II)]
title Bis(μ-quinoline-2-carboxyl­ato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)(methanol-κO)lead(II)]
title_full Bis(μ-quinoline-2-carboxyl­ato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)(methanol-κO)lead(II)]
title_fullStr Bis(μ-quinoline-2-carboxyl­ato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)(methanol-κO)lead(II)]
title_full_unstemmed Bis(μ-quinoline-2-carboxyl­ato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)(methanol-κO)lead(II)]
title_short Bis(μ-quinoline-2-carboxyl­ato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)(methanol-κO)lead(II)]
title_sort bis(μ-quinoline-2-carboxyl­ato)-κ(3) n,o:o;κ(3) o:n,o-bis­[(acetato-κ(2) o,o′)(methanol-κo)lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007209/
https://www.ncbi.nlm.nih.gov/pubmed/21588188
http://dx.doi.org/10.1107/S1600536810027777
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