Dichloridobis(isoquinoline-κN)zinc(II)

In the title compound, [ZnCl(2)(C(9)H(7)N)(2)], the Zn(II) cation is coordinated by two Cl(−) anions and two isoquinoline ligands in a distorted ZnCl(2)N(2) tetra­hedral geometry; the two isoquinoline ring systems are twisted with respect to each other at a dihedral angle of 45.72 (8)°. The parallel...

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Detalles Bibliográficos
Autores principales: Li, Meng-Jiao, Nie, Jing-Jing, Xu, Duan-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007211/
https://www.ncbi.nlm.nih.gov/pubmed/21588123
http://dx.doi.org/10.1107/S1600536810024803
Descripción
Sumario:In the title compound, [ZnCl(2)(C(9)H(7)N)(2)], the Zn(II) cation is coordinated by two Cl(−) anions and two isoquinoline ligands in a distorted ZnCl(2)N(2) tetra­hedral geometry; the two isoquinoline ring systems are twisted with respect to each other at a dihedral angle of 45.72 (8)°. The parallel isoqiunoline ring systems of adjacent mol­ecules are partially overlapped, with the shorter face-to-face distance of 3.438 (19) Å indicating the existence of weak π–π stacking in the crystal structure.

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