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Dichloridobis(isoquinoline-κN)zinc(II)
In the title compound, [ZnCl(2)(C(9)H(7)N)(2)], the Zn(II) cation is coordinated by two Cl(−) anions and two isoquinoline ligands in a distorted ZnCl(2)N(2) tetrahedral geometry; the two isoquinoline ring systems are twisted with respect to each other at a dihedral angle of 45.72 (8)°. The parallel...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007211/ https://www.ncbi.nlm.nih.gov/pubmed/21588123 http://dx.doi.org/10.1107/S1600536810024803 |
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| author | Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun |
| author_facet | Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun |
| author_sort | Li, Meng-Jiao |
| collection | PubMed |
| description | In the title compound, [ZnCl(2)(C(9)H(7)N)(2)], the Zn(II) cation is coordinated by two Cl(−) anions and two isoquinoline ligands in a distorted ZnCl(2)N(2) tetrahedral geometry; the two isoquinoline ring systems are twisted with respect to each other at a dihedral angle of 45.72 (8)°. The parallel isoqiunoline ring systems of adjacent molecules are partially overlapped, with the shorter face-to-face distance of 3.438 (19) Å indicating the existence of weak π–π stacking in the crystal structure. |
| format | Text |
| id | pubmed-3007211 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30072112010-12-30 Dichloridobis(isoquinoline-κN)zinc(II) Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(9)H(7)N)(2)], the Zn(II) cation is coordinated by two Cl(−) anions and two isoquinoline ligands in a distorted ZnCl(2)N(2) tetrahedral geometry; the two isoquinoline ring systems are twisted with respect to each other at a dihedral angle of 45.72 (8)°. The parallel isoqiunoline ring systems of adjacent molecules are partially overlapped, with the shorter face-to-face distance of 3.438 (19) Å indicating the existence of weak π–π stacking in the crystal structure. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007211/ /pubmed/21588123 http://dx.doi.org/10.1107/S1600536810024803 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun Dichloridobis(isoquinoline-κN)zinc(II) |
| title | Dichloridobis(isoquinoline-κN)zinc(II) |
| title_full | Dichloridobis(isoquinoline-κN)zinc(II) |
| title_fullStr | Dichloridobis(isoquinoline-κN)zinc(II) |
| title_full_unstemmed | Dichloridobis(isoquinoline-κN)zinc(II) |
| title_short | Dichloridobis(isoquinoline-κN)zinc(II) |
| title_sort | dichloridobis(isoquinoline-κn)zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007211/ https://www.ncbi.nlm.nih.gov/pubmed/21588123 http://dx.doi.org/10.1107/S1600536810024803 |
| work_keys_str_mv | AT limengjiao dichloridobisisoquinolineknzincii AT niejingjing dichloridobisisoquinolineknzincii AT xuduanjun dichloridobisisoquinolineknzincii |