3-[(2-Hy­droxy-1-naphth­yl)(pyrrolidin-1-yl)meth­yl]benzonitrile

The title compound, C(22)H(20)N(2)O, was obtained from the condensation reaction of 3-formyl­benzonitrile, 2-naphthol and pyrrolidine. There are two mol­ecules in the asymmetric unit, having similar conformations. Intra­molecular O—H⋯N and C—H⋯O hydrogen bonds occur, with only van der Waals forces b...

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Detalles Bibliográficos
Autor principal: Xue, Meng Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007212/
https://www.ncbi.nlm.nih.gov/pubmed/21588320
http://dx.doi.org/10.1107/S1600536810026152
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author Xue, Meng Wei
author_facet Xue, Meng Wei
author_sort Xue, Meng Wei
collection PubMed
description The title compound, C(22)H(20)N(2)O, was obtained from the condensation reaction of 3-formyl­benzonitrile, 2-naphthol and pyrrolidine. There are two mol­ecules in the asymmetric unit, having similar conformations. Intra­molecular O—H⋯N and C—H⋯O hydrogen bonds occur, with only van der Waals forces between mol­ecules. The dihedral angles between the naphthalene ring system and the phenyl ring in the two molecules are 75.28 (10) and 76.07 (11)°. The five-membered rings adopt half-chair conformations.
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spelling pubmed-30072122010-12-30 3-[(2-Hy­droxy-1-naphth­yl)(pyrrolidin-1-yl)meth­yl]benzonitrile Xue, Meng Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(20)N(2)O, was obtained from the condensation reaction of 3-formyl­benzonitrile, 2-naphthol and pyrrolidine. There are two mol­ecules in the asymmetric unit, having similar conformations. Intra­molecular O—H⋯N and C—H⋯O hydrogen bonds occur, with only van der Waals forces between mol­ecules. The dihedral angles between the naphthalene ring system and the phenyl ring in the two molecules are 75.28 (10) and 76.07 (11)°. The five-membered rings adopt half-chair conformations. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007212/ /pubmed/21588320 http://dx.doi.org/10.1107/S1600536810026152 Text en © Meng Wei Xue 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xue, Meng Wei
3-[(2-Hy­droxy-1-naphth­yl)(pyrrolidin-1-yl)meth­yl]benzonitrile
title 3-[(2-Hy­droxy-1-naphth­yl)(pyrrolidin-1-yl)meth­yl]benzonitrile
title_full 3-[(2-Hy­droxy-1-naphth­yl)(pyrrolidin-1-yl)meth­yl]benzonitrile
title_fullStr 3-[(2-Hy­droxy-1-naphth­yl)(pyrrolidin-1-yl)meth­yl]benzonitrile
title_full_unstemmed 3-[(2-Hy­droxy-1-naphth­yl)(pyrrolidin-1-yl)meth­yl]benzonitrile
title_short 3-[(2-Hy­droxy-1-naphth­yl)(pyrrolidin-1-yl)meth­yl]benzonitrile
title_sort 3-[(2-hy­droxy-1-naphth­yl)(pyrrolidin-1-yl)meth­yl]benzonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007212/
https://www.ncbi.nlm.nih.gov/pubmed/21588320
http://dx.doi.org/10.1107/S1600536810026152
work_keys_str_mv AT xuemengwei 32hydroxy1naphthylpyrrolidin1ylmethylbenzonitrile

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