Diethyl 4-hy­droxy-4-methyl-6-oxo-2-phenyl­cyclo­hexane-1,3-dicarboxyl­ate

In the title mol­ecule, C(19)H(24)O(6), the cyclo­hexa­none ring adopts a chair conformation. The dihedral angle between the phenyl ring and the best plane through the six atoms of the cyclo­hexa­none ring is 89.68 (7)°. In the crystal structure, mol­ecules are linked via pairs of inter­molecular O—...

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Autores principales: Fun, Hoong-Kun, Hemamalini, Madhukar, Padaki, Mahesh, Isloor, Arun M
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007213/
https://www.ncbi.nlm.nih.gov/pubmed/21588242
http://dx.doi.org/10.1107/S1600536810025018
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author Fun, Hoong-Kun
Hemamalini, Madhukar
Padaki, Mahesh
Isloor, Arun M
author_facet Fun, Hoong-Kun
Hemamalini, Madhukar
Padaki, Mahesh
Isloor, Arun M
author_sort Fun, Hoong-Kun
collection PubMed
description In the title mol­ecule, C(19)H(24)O(6), the cyclo­hexa­none ring adopts a chair conformation. The dihedral angle between the phenyl ring and the best plane through the six atoms of the cyclo­hexa­none ring is 89.68 (7)°. In the crystal structure, mol­ecules are linked via pairs of inter­molecular O—H⋯O hydrogen bonds into centrosymmetric dimers and these dimers are connected by C—H⋯O inter­actions into columns down the a axis.
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spelling pubmed-30072132010-12-30 Diethyl 4-hy­droxy-4-methyl-6-oxo-2-phenyl­cyclo­hexane-1,3-dicarboxyl­ate Fun, Hoong-Kun Hemamalini, Madhukar Padaki, Mahesh Isloor, Arun M Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(19)H(24)O(6), the cyclo­hexa­none ring adopts a chair conformation. The dihedral angle between the phenyl ring and the best plane through the six atoms of the cyclo­hexa­none ring is 89.68 (7)°. In the crystal structure, mol­ecules are linked via pairs of inter­molecular O—H⋯O hydrogen bonds into centrosymmetric dimers and these dimers are connected by C—H⋯O inter­actions into columns down the a axis. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007213/ /pubmed/21588242 http://dx.doi.org/10.1107/S1600536810025018 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Hemamalini, Madhukar
Padaki, Mahesh
Isloor, Arun M
Diethyl 4-hy­droxy-4-methyl-6-oxo-2-phenyl­cyclo­hexane-1,3-dicarboxyl­ate
title Diethyl 4-hy­droxy-4-methyl-6-oxo-2-phenyl­cyclo­hexane-1,3-dicarboxyl­ate
title_full Diethyl 4-hy­droxy-4-methyl-6-oxo-2-phenyl­cyclo­hexane-1,3-dicarboxyl­ate
title_fullStr Diethyl 4-hy­droxy-4-methyl-6-oxo-2-phenyl­cyclo­hexane-1,3-dicarboxyl­ate
title_full_unstemmed Diethyl 4-hy­droxy-4-methyl-6-oxo-2-phenyl­cyclo­hexane-1,3-dicarboxyl­ate
title_short Diethyl 4-hy­droxy-4-methyl-6-oxo-2-phenyl­cyclo­hexane-1,3-dicarboxyl­ate
title_sort diethyl 4-hy­droxy-4-methyl-6-oxo-2-phenyl­cyclo­hexane-1,3-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007213/
https://www.ncbi.nlm.nih.gov/pubmed/21588242
http://dx.doi.org/10.1107/S1600536810025018
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AT padakimahesh diethyl4hydroxy4methyl6oxo2phenylcyclohexane13dicarboxylate
AT isloorarunm diethyl4hydroxy4methyl6oxo2phenylcyclohexane13dicarboxylate

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