Tetra­kis(4-cyano­pyridine)­palladium(II) bis­(trifluoro­methane­sulfonate)

The title salt, [Pd(C(6)H(4)N(2))(4)](CF(3)SO(3))(2), comprises Pd(4-cyano­pyridine)(4) dications balanced by two trifluoro­methane­sulfonate anions. The Pd(II) atom lies in a square-planar geometry defined by four N atoms which form equivalent Pd—N inter­actions. The 4-cyano­pyridine ligands are tw...

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Detalles Bibliográficos
Autores principales: Adrian, Rafael A., Gonzalez, David M., Tiekink, Edward R. T., Walmsley, Judith A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007218/
https://www.ncbi.nlm.nih.gov/pubmed/21588185
http://dx.doi.org/10.1107/S1600536810027704
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author Adrian, Rafael A.
Gonzalez, David M.
Tiekink, Edward R. T.
Walmsley, Judith A.
author_facet Adrian, Rafael A.
Gonzalez, David M.
Tiekink, Edward R. T.
Walmsley, Judith A.
author_sort Adrian, Rafael A.
collection PubMed
description The title salt, [Pd(C(6)H(4)N(2))(4)](CF(3)SO(3))(2), comprises Pd(4-cyano­pyridine)(4) dications balanced by two trifluoro­methane­sulfonate anions. The Pd(II) atom lies in a square-planar geometry defined by four N atoms which form equivalent Pd—N inter­actions. The 4-cyano­pyridine ligands are twisted out of the N(4) plane, forming dihedral angles ranging from 66.5 (2) to 89.9 (2)°. In the crystal packing, columns of edge-to-edge dications define channels in which reside the anions. A range of C—H⋯N and C—H⋯O hydrogen-bonding interactions stabilizes the crystal packing.
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spelling pubmed-30072182010-12-30 Tetra­kis(4-cyano­pyridine)­palladium(II) bis­(trifluoro­methane­sulfonate) Adrian, Rafael A. Gonzalez, David M. Tiekink, Edward R. T. Walmsley, Judith A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, [Pd(C(6)H(4)N(2))(4)](CF(3)SO(3))(2), comprises Pd(4-cyano­pyridine)(4) dications balanced by two trifluoro­methane­sulfonate anions. The Pd(II) atom lies in a square-planar geometry defined by four N atoms which form equivalent Pd—N inter­actions. The 4-cyano­pyridine ligands are twisted out of the N(4) plane, forming dihedral angles ranging from 66.5 (2) to 89.9 (2)°. In the crystal packing, columns of edge-to-edge dications define channels in which reside the anions. A range of C—H⋯N and C—H⋯O hydrogen-bonding interactions stabilizes the crystal packing. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007218/ /pubmed/21588185 http://dx.doi.org/10.1107/S1600536810027704 Text en © Adrian et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Adrian, Rafael A.
Gonzalez, David M.
Tiekink, Edward R. T.
Walmsley, Judith A.
Tetra­kis(4-cyano­pyridine)­palladium(II) bis­(trifluoro­methane­sulfonate)
title Tetra­kis(4-cyano­pyridine)­palladium(II) bis­(trifluoro­methane­sulfonate)
title_full Tetra­kis(4-cyano­pyridine)­palladium(II) bis­(trifluoro­methane­sulfonate)
title_fullStr Tetra­kis(4-cyano­pyridine)­palladium(II) bis­(trifluoro­methane­sulfonate)
title_full_unstemmed Tetra­kis(4-cyano­pyridine)­palladium(II) bis­(trifluoro­methane­sulfonate)
title_short Tetra­kis(4-cyano­pyridine)­palladium(II) bis­(trifluoro­methane­sulfonate)
title_sort tetra­kis(4-cyano­pyridine)­palladium(ii) bis­(trifluoro­methane­sulfonate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007218/
https://www.ncbi.nlm.nih.gov/pubmed/21588185
http://dx.doi.org/10.1107/S1600536810027704
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AT tiekinkedwardrt tetrakis4cyanopyridinepalladiumiibistrifluoromethanesulfonate
AT walmsleyjuditha tetrakis4cyanopyridinepalladiumiibistrifluoromethanesulfonate

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