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{2-[2-(Carboxymethoxy)phenoxy]acetato}[2,2′-(o-phenylenedioxy)diacetic acid]sodium 4,4′-bipyridine hemisolvate monohydrate
In the title compound, [Na(C(10)H(9)O(6))(C(10)H(10)O(6))]·0.5C(10)H(8)N(2)·H(2)O, the Na atom is eight-coordinated in an distorted dicapped-octahedral geometry by eight O atoms from a 2-(2-carboxymethoxyphenoxy)acetate (o-BDOAH) anion and a 2,2′-(o-phenylenedioxy)diacetic acid (o-BDOAH(2))...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007220/ https://www.ncbi.nlm.nih.gov/pubmed/21588116 http://dx.doi.org/10.1107/S1600536810024797 |
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| author | Xu, Liang Gu, Li-Yan Yang, Yan-Yun Wang, Bing Kang, Ting-Guo |
| author_facet | Xu, Liang Gu, Li-Yan Yang, Yan-Yun Wang, Bing Kang, Ting-Guo |
| author_sort | Xu, Liang |
| collection | PubMed |
| description | In the title compound, [Na(C(10)H(9)O(6))(C(10)H(10)O(6))]·0.5C(10)H(8)N(2)·H(2)O, the Na atom is eight-coordinated in an distorted dicapped-octahedral geometry by eight O atoms from a 2-(2-carboxymethoxyphenoxy)acetate (o-BDOAH) anion and a 2,2′-(o-phenylenedioxy)diacetic acid (o-BDOAH(2)) molecule. The uncoordinated 4,4′-bipyridine molecule is arranged around an inversion center and exhibits rotational disorder. A three-dimensional supramolecular network is built up in the crystal through O—H⋯O and O—H⋯N hydrogen bonds between the uncoordinated water molecule, the uncoordinated 4,4′-bipyridine molecule and the sodium complex molecule. |
| format | Text |
| id | pubmed-3007220 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30072202010-12-30 {2-[2-(Carboxymethoxy)phenoxy]acetato}[2,2′-(o-phenylenedioxy)diacetic acid]sodium 4,4′-bipyridine hemisolvate monohydrate Xu, Liang Gu, Li-Yan Yang, Yan-Yun Wang, Bing Kang, Ting-Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Na(C(10)H(9)O(6))(C(10)H(10)O(6))]·0.5C(10)H(8)N(2)·H(2)O, the Na atom is eight-coordinated in an distorted dicapped-octahedral geometry by eight O atoms from a 2-(2-carboxymethoxyphenoxy)acetate (o-BDOAH) anion and a 2,2′-(o-phenylenedioxy)diacetic acid (o-BDOAH(2)) molecule. The uncoordinated 4,4′-bipyridine molecule is arranged around an inversion center and exhibits rotational disorder. A three-dimensional supramolecular network is built up in the crystal through O—H⋯O and O—H⋯N hydrogen bonds between the uncoordinated water molecule, the uncoordinated 4,4′-bipyridine molecule and the sodium complex molecule. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007220/ /pubmed/21588116 http://dx.doi.org/10.1107/S1600536810024797 Text en © Xu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xu, Liang Gu, Li-Yan Yang, Yan-Yun Wang, Bing Kang, Ting-Guo {2-[2-(Carboxymethoxy)phenoxy]acetato}[2,2′-(o-phenylenedioxy)diacetic acid]sodium 4,4′-bipyridine hemisolvate monohydrate |
| title | {2-[2-(Carboxymethoxy)phenoxy]acetato}[2,2′-(o-phenylenedioxy)diacetic acid]sodium 4,4′-bipyridine hemisolvate monohydrate |
| title_full | {2-[2-(Carboxymethoxy)phenoxy]acetato}[2,2′-(o-phenylenedioxy)diacetic acid]sodium 4,4′-bipyridine hemisolvate monohydrate |
| title_fullStr | {2-[2-(Carboxymethoxy)phenoxy]acetato}[2,2′-(o-phenylenedioxy)diacetic acid]sodium 4,4′-bipyridine hemisolvate monohydrate |
| title_full_unstemmed | {2-[2-(Carboxymethoxy)phenoxy]acetato}[2,2′-(o-phenylenedioxy)diacetic acid]sodium 4,4′-bipyridine hemisolvate monohydrate |
| title_short | {2-[2-(Carboxymethoxy)phenoxy]acetato}[2,2′-(o-phenylenedioxy)diacetic acid]sodium 4,4′-bipyridine hemisolvate monohydrate |
| title_sort | {2-[2-(carboxymethoxy)phenoxy]acetato}[2,2′-(o-phenylenedioxy)diacetic acid]sodium 4,4′-bipyridine hemisolvate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007220/ https://www.ncbi.nlm.nih.gov/pubmed/21588116 http://dx.doi.org/10.1107/S1600536810024797 |
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