5,8-Dibromo-15,18-dimeth­oxy-2,11-dithia­[3.3]paracyclo­phane

In the title compound [systematic name: 1(2),1(5)-dibromo-5(2),5(5)-dimethoxy-2,7-dithia-1,5(1,4)-dibenzenaoctaphane], C(18)H(18)Br(2)O(2)S(2), the dihedral angle between the aromatic rings is 0.6 (2)° and their centroid separation is 3.251 (2) Å, indicating that a trans-annular π–π interaction occu...

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Detalles Bibliográficos
Autores principales: Jin, Guojun, Lu, Yinghui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007221/
https://www.ncbi.nlm.nih.gov/pubmed/21588431
http://dx.doi.org/10.1107/S1600536810029053
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author Jin, Guojun
Lu, Yinghui
author_facet Jin, Guojun
Lu, Yinghui
author_sort Jin, Guojun
collection PubMed
description In the title compound [systematic name: 1(2),1(5)-dibromo-5(2),5(5)-dimethoxy-2,7-dithia-1,5(1,4)-dibenzenaoctaphane], C(18)H(18)Br(2)O(2)S(2), the dihedral angle between the aromatic rings is 0.6 (2)° and their centroid separation is 3.251 (2) Å, indicating that a trans-annular π–π interaction occurs. The dimeth­oxy and dibromo substituents are located at crossed positions because of the electronic and the steric nature of the substituents.
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spelling pubmed-30072212010-12-30 5,8-Dibromo-15,18-dimeth­oxy-2,11-dithia­[3.3]paracyclo­phane Jin, Guojun Lu, Yinghui Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound [systematic name: 1(2),1(5)-dibromo-5(2),5(5)-dimethoxy-2,7-dithia-1,5(1,4)-dibenzenaoctaphane], C(18)H(18)Br(2)O(2)S(2), the dihedral angle between the aromatic rings is 0.6 (2)° and their centroid separation is 3.251 (2) Å, indicating that a trans-annular π–π interaction occurs. The dimeth­oxy and dibromo substituents are located at crossed positions because of the electronic and the steric nature of the substituents. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007221/ /pubmed/21588431 http://dx.doi.org/10.1107/S1600536810029053 Text en © Jin and Lu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jin, Guojun
Lu, Yinghui
5,8-Dibromo-15,18-dimeth­oxy-2,11-dithia­[3.3]paracyclo­phane
title 5,8-Dibromo-15,18-dimeth­oxy-2,11-dithia­[3.3]paracyclo­phane
title_full 5,8-Dibromo-15,18-dimeth­oxy-2,11-dithia­[3.3]paracyclo­phane
title_fullStr 5,8-Dibromo-15,18-dimeth­oxy-2,11-dithia­[3.3]paracyclo­phane
title_full_unstemmed 5,8-Dibromo-15,18-dimeth­oxy-2,11-dithia­[3.3]paracyclo­phane
title_short 5,8-Dibromo-15,18-dimeth­oxy-2,11-dithia­[3.3]paracyclo­phane
title_sort 5,8-dibromo-15,18-dimeth­oxy-2,11-dithia­[3.3]paracyclo­phane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007221/
https://www.ncbi.nlm.nih.gov/pubmed/21588431
http://dx.doi.org/10.1107/S1600536810029053
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AT luyinghui 58dibromo1518dimethoxy211dithia33paracyclophane

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