Poly[tetra-μ(1,1)-azido-bis­(μ(2)-pyrimidine-2-carboxyl­ato)tricopper(II)]

In the title compound, [Cu(3)(C(5)H(3)N(2)O(2))(2)(N(3))(4)](n), one of the Cu(II) atoms lies on an inversion centre and is octa­hedrally coordinated by two bidentate chelating pyrimidine-2-carboxyl­ate ligands and two azide anions, each of which gives an N:N-bridge to the second inversion-related C...

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Detalles Bibliográficos
Autores principales: Zhao, Jiong-Peng, Liu, Fu-Chen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007223/
https://www.ncbi.nlm.nih.gov/pubmed/21588197
http://dx.doi.org/10.1107/S1600536810027030
Descripción
Sumario:In the title compound, [Cu(3)(C(5)H(3)N(2)O(2))(2)(N(3))(4)](n), one of the Cu(II) atoms lies on an inversion centre and is octa­hedrally coordinated by two bidentate chelating pyrimidine-2-carboxyl­ate ligands and two azide anions, each of which gives an N:N-bridge to the second inversion-related Cu(II) centre in the formula unit. The second Cu(II) atom is five-coordinated with a distorted square-pyramidal coordination sphere comprising a single bidentate chelating pyrimidine-2-carboxyl­ate anion and three azide N anions, two of which doubly bridge centrosymmetric Cu(II) centres, giving a two-dimensional network structure extending parallel to (010).

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