Poly[tetra-μ(1,1)-azido-bis­(μ(2)-pyrimidine-2-carboxyl­ato)tricopper(II)]

In the title compound, [Cu(3)(C(5)H(3)N(2)O(2))(2)(N(3))(4)](n), one of the Cu(II) atoms lies on an inversion centre and is octa­hedrally coordinated by two bidentate chelating pyrimidine-2-carboxyl­ate ligands and two azide anions, each of which gives an N:N-bridge to the second inversion-related C...

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Detalles Bibliográficos
Autores principales: Zhao, Jiong-Peng, Liu, Fu-Chen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007223/
https://www.ncbi.nlm.nih.gov/pubmed/21588197
http://dx.doi.org/10.1107/S1600536810027030
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author Zhao, Jiong-Peng
Liu, Fu-Chen
author_facet Zhao, Jiong-Peng
Liu, Fu-Chen
author_sort Zhao, Jiong-Peng
collection PubMed
description In the title compound, [Cu(3)(C(5)H(3)N(2)O(2))(2)(N(3))(4)](n), one of the Cu(II) atoms lies on an inversion centre and is octa­hedrally coordinated by two bidentate chelating pyrimidine-2-carboxyl­ate ligands and two azide anions, each of which gives an N:N-bridge to the second inversion-related Cu(II) centre in the formula unit. The second Cu(II) atom is five-coordinated with a distorted square-pyramidal coordination sphere comprising a single bidentate chelating pyrimidine-2-carboxyl­ate anion and three azide N anions, two of which doubly bridge centrosymmetric Cu(II) centres, giving a two-dimensional network structure extending parallel to (010).
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spelling pubmed-30072232010-12-30 Poly[tetra-μ(1,1)-azido-bis­(μ(2)-pyrimidine-2-carboxyl­ato)tricopper(II)] Zhao, Jiong-Peng Liu, Fu-Chen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(3)(C(5)H(3)N(2)O(2))(2)(N(3))(4)](n), one of the Cu(II) atoms lies on an inversion centre and is octa­hedrally coordinated by two bidentate chelating pyrimidine-2-carboxyl­ate ligands and two azide anions, each of which gives an N:N-bridge to the second inversion-related Cu(II) centre in the formula unit. The second Cu(II) atom is five-coordinated with a distorted square-pyramidal coordination sphere comprising a single bidentate chelating pyrimidine-2-carboxyl­ate anion and three azide N anions, two of which doubly bridge centrosymmetric Cu(II) centres, giving a two-dimensional network structure extending parallel to (010). International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007223/ /pubmed/21588197 http://dx.doi.org/10.1107/S1600536810027030 Text en © Zhao and Liu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Jiong-Peng
Liu, Fu-Chen
Poly[tetra-μ(1,1)-azido-bis­(μ(2)-pyrimidine-2-carboxyl­ato)tricopper(II)]
title Poly[tetra-μ(1,1)-azido-bis­(μ(2)-pyrimidine-2-carboxyl­ato)tricopper(II)]
title_full Poly[tetra-μ(1,1)-azido-bis­(μ(2)-pyrimidine-2-carboxyl­ato)tricopper(II)]
title_fullStr Poly[tetra-μ(1,1)-azido-bis­(μ(2)-pyrimidine-2-carboxyl­ato)tricopper(II)]
title_full_unstemmed Poly[tetra-μ(1,1)-azido-bis­(μ(2)-pyrimidine-2-carboxyl­ato)tricopper(II)]
title_short Poly[tetra-μ(1,1)-azido-bis­(μ(2)-pyrimidine-2-carboxyl­ato)tricopper(II)]
title_sort poly[tetra-μ(1,1)-azido-bis­(μ(2)-pyrimidine-2-carboxyl­ato)tricopper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007223/
https://www.ncbi.nlm.nih.gov/pubmed/21588197
http://dx.doi.org/10.1107/S1600536810027030
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