3-Acetyl-2-methyl-4-phenyl­quinolin-1-ium chloride

An N—H⋯Cl hydrogen bond connects the ions in the title salt, C(18)H(16)NO(+)·Cl(−). The quinolin-1-ium residue is almost planar (r.m.s. deviation = 0.020 Å) but both the acetyl group [O—C—C—C torsion angle = 62.73 (17)°] and adjacent benzene ring [C—C—C—C torsion angle = −104.06 (14)°] are twisted o...

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Autores principales: Kiran, K., Sarveswari, S., Vijayakumar, V., Tan, Kang Wai, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007226/
https://www.ncbi.nlm.nih.gov/pubmed/21588315
http://dx.doi.org/10.1107/S1600536810027017
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author Kiran, K.
Sarveswari, S.
Vijayakumar, V.
Tan, Kang Wai
Tiekink, Edward R. T.
author_facet Kiran, K.
Sarveswari, S.
Vijayakumar, V.
Tan, Kang Wai
Tiekink, Edward R. T.
author_sort Kiran, K.
collection PubMed
description An N—H⋯Cl hydrogen bond connects the ions in the title salt, C(18)H(16)NO(+)·Cl(−). The quinolin-1-ium residue is almost planar (r.m.s. deviation = 0.020 Å) but both the acetyl group [O—C—C—C torsion angle = 62.73 (17)°] and adjacent benzene ring [C—C—C—C torsion angle = −104.06 (14)°] are twisted out of this plane; the acetyl and benzene substituents are non-parallel [dihedral angle = 66.16 (7)°]. The crystal packing is consolidated by C—H⋯O and C—H⋯Cl contacts.
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spelling pubmed-30072262010-12-30 3-Acetyl-2-methyl-4-phenyl­quinolin-1-ium chloride Kiran, K. Sarveswari, S. Vijayakumar, V. Tan, Kang Wai Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers An N—H⋯Cl hydrogen bond connects the ions in the title salt, C(18)H(16)NO(+)·Cl(−). The quinolin-1-ium residue is almost planar (r.m.s. deviation = 0.020 Å) but both the acetyl group [O—C—C—C torsion angle = 62.73 (17)°] and adjacent benzene ring [C—C—C—C torsion angle = −104.06 (14)°] are twisted out of this plane; the acetyl and benzene substituents are non-parallel [dihedral angle = 66.16 (7)°]. The crystal packing is consolidated by C—H⋯O and C—H⋯Cl contacts. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007226/ /pubmed/21588315 http://dx.doi.org/10.1107/S1600536810027017 Text en © Kiran et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kiran, K.
Sarveswari, S.
Vijayakumar, V.
Tan, Kang Wai
Tiekink, Edward R. T.
3-Acetyl-2-methyl-4-phenyl­quinolin-1-ium chloride
title 3-Acetyl-2-methyl-4-phenyl­quinolin-1-ium chloride
title_full 3-Acetyl-2-methyl-4-phenyl­quinolin-1-ium chloride
title_fullStr 3-Acetyl-2-methyl-4-phenyl­quinolin-1-ium chloride
title_full_unstemmed 3-Acetyl-2-methyl-4-phenyl­quinolin-1-ium chloride
title_short 3-Acetyl-2-methyl-4-phenyl­quinolin-1-ium chloride
title_sort 3-acetyl-2-methyl-4-phenyl­quinolin-1-ium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007226/
https://www.ncbi.nlm.nih.gov/pubmed/21588315
http://dx.doi.org/10.1107/S1600536810027017
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AT sarveswaris 3acetyl2methyl4phenylquinolin1iumchloride
AT vijayakumarv 3acetyl2methyl4phenylquinolin1iumchloride
AT tankangwai 3acetyl2methyl4phenylquinolin1iumchloride
AT tiekinkedwardrt 3acetyl2methyl4phenylquinolin1iumchloride

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