3-Benzyl-3-hy­droxy-2-phenyl-3H-indole 1-oxide

The asymmetric unit of the title compound, C(21)H(17)NO(2), contains two crystallographically independent mol­ecules of similar geometry. The indole ring systems form dihedral angles of 8.30 (5) and 9.58 (5)° with the attached phenyl rings, and 56.96 (5) and 57.68 (5)° with the aromatic rings of the...

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Detalles Bibliográficos
Autores principales: Rizzoli, Corrado, Astolfi, Paola, Marku, Elda, Greci, Lucedio
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007230/
https://www.ncbi.nlm.nih.gov/pubmed/21588302
http://dx.doi.org/10.1107/S1600536810026176
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author Rizzoli, Corrado
Astolfi, Paola
Marku, Elda
Greci, Lucedio
author_facet Rizzoli, Corrado
Astolfi, Paola
Marku, Elda
Greci, Lucedio
author_sort Rizzoli, Corrado
collection PubMed
description The asymmetric unit of the title compound, C(21)H(17)NO(2), contains two crystallographically independent mol­ecules of similar geometry. The indole ring systems form dihedral angles of 8.30 (5) and 9.58 (5)° with the attached phenyl rings, and 56.96 (5) and 57.68 (5)° with the aromatic rings of the respective benzyl groups. The mol­ecular conformations are stabilized by intra­molecular C—H⋯O hydrogen bonds. In the crystal structure, centrosymmetrically related pairs of mol­ecules are linked into dimers through pairs of inter­molecular O—H⋯O hydrogen bonds, generating 12-membered rings with R (2) (2)(12) motifs. The dimers are further linked into a three-dimensional network by C—H⋯O inter­actions.
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spelling pubmed-30072302010-12-30 3-Benzyl-3-hy­droxy-2-phenyl-3H-indole 1-oxide Rizzoli, Corrado Astolfi, Paola Marku, Elda Greci, Lucedio Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(21)H(17)NO(2), contains two crystallographically independent mol­ecules of similar geometry. The indole ring systems form dihedral angles of 8.30 (5) and 9.58 (5)° with the attached phenyl rings, and 56.96 (5) and 57.68 (5)° with the aromatic rings of the respective benzyl groups. The mol­ecular conformations are stabilized by intra­molecular C—H⋯O hydrogen bonds. In the crystal structure, centrosymmetrically related pairs of mol­ecules are linked into dimers through pairs of inter­molecular O—H⋯O hydrogen bonds, generating 12-membered rings with R (2) (2)(12) motifs. The dimers are further linked into a three-dimensional network by C—H⋯O inter­actions. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007230/ /pubmed/21588302 http://dx.doi.org/10.1107/S1600536810026176 Text en © Rizzoli et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rizzoli, Corrado
Astolfi, Paola
Marku, Elda
Greci, Lucedio
3-Benzyl-3-hy­droxy-2-phenyl-3H-indole 1-oxide
title 3-Benzyl-3-hy­droxy-2-phenyl-3H-indole 1-oxide
title_full 3-Benzyl-3-hy­droxy-2-phenyl-3H-indole 1-oxide
title_fullStr 3-Benzyl-3-hy­droxy-2-phenyl-3H-indole 1-oxide
title_full_unstemmed 3-Benzyl-3-hy­droxy-2-phenyl-3H-indole 1-oxide
title_short 3-Benzyl-3-hy­droxy-2-phenyl-3H-indole 1-oxide
title_sort 3-benzyl-3-hy­droxy-2-phenyl-3h-indole 1-oxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007230/
https://www.ncbi.nlm.nih.gov/pubmed/21588302
http://dx.doi.org/10.1107/S1600536810026176
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AT astolfipaola 3benzyl3hydroxy2phenyl3hindole1oxide
AT markuelda 3benzyl3hydroxy2phenyl3hindole1oxide
AT grecilucedio 3benzyl3hydroxy2phenyl3hindole1oxide

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