9,9-Bis[4-(prop-2-yn­yloxy)phen­yl]-9H-fluorene

In the title compound, C(31)H(22)O(2), the bond angle at the C atom belonging to the five-membered ring of the fluorene system is opened to 112.64 (12)°. The two benzene rings are twisted with respect to the fluorene ring system at dihedral angles of 72.81 (6) and 81.83 (6)°. One C(ar­yl)—O—C—C  fra...

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Detalles Bibliográficos
Autores principales: Shah, Kiramat, Raza Shah, Muhammad, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007235/
https://www.ncbi.nlm.nih.gov/pubmed/21588265
http://dx.doi.org/10.1107/S1600536810025833
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author Shah, Kiramat
Raza Shah, Muhammad
Ng, Seik Weng
author_facet Shah, Kiramat
Raza Shah, Muhammad
Ng, Seik Weng
author_sort Shah, Kiramat
collection PubMed
description In the title compound, C(31)H(22)O(2), the bond angle at the C atom belonging to the five-membered ring of the fluorene system is opened to 112.64 (12)°. The two benzene rings are twisted with respect to the fluorene ring system at dihedral angles of 72.81 (6) and 81.83 (6)°. One C(ar­yl)—O—C—C  fragment is extended, with a C—O—C—C torsion angle of −178.77 (13)°, but the other C(ar­yl)—O—C—C  fragment is bent, with a C—O—C—C torsion angle of 64.78 (19)°. Inter­molecular weak C—H⋯O hydrogen bonding is present in the crystal structure.
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spelling pubmed-30072352010-12-30 9,9-Bis[4-(prop-2-yn­yloxy)phen­yl]-9H-fluorene Shah, Kiramat Raza Shah, Muhammad Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(31)H(22)O(2), the bond angle at the C atom belonging to the five-membered ring of the fluorene system is opened to 112.64 (12)°. The two benzene rings are twisted with respect to the fluorene ring system at dihedral angles of 72.81 (6) and 81.83 (6)°. One C(ar­yl)—O—C—C  fragment is extended, with a C—O—C—C torsion angle of −178.77 (13)°, but the other C(ar­yl)—O—C—C  fragment is bent, with a C—O—C—C torsion angle of 64.78 (19)°. Inter­molecular weak C—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007235/ /pubmed/21588265 http://dx.doi.org/10.1107/S1600536810025833 Text en © Shah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shah, Kiramat
Raza Shah, Muhammad
Ng, Seik Weng
9,9-Bis[4-(prop-2-yn­yloxy)phen­yl]-9H-fluorene
title 9,9-Bis[4-(prop-2-yn­yloxy)phen­yl]-9H-fluorene
title_full 9,9-Bis[4-(prop-2-yn­yloxy)phen­yl]-9H-fluorene
title_fullStr 9,9-Bis[4-(prop-2-yn­yloxy)phen­yl]-9H-fluorene
title_full_unstemmed 9,9-Bis[4-(prop-2-yn­yloxy)phen­yl]-9H-fluorene
title_short 9,9-Bis[4-(prop-2-yn­yloxy)phen­yl]-9H-fluorene
title_sort 9,9-bis[4-(prop-2-yn­yloxy)phen­yl]-9h-fluorene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007235/
https://www.ncbi.nlm.nih.gov/pubmed/21588265
http://dx.doi.org/10.1107/S1600536810025833
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