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3-Chlorobenzohydrazide
In the title compound, C(7)H(7)ClN(2)O, the hydrazide group is inclined at a dihedral angle of 32.30 (11)° with respect to the benzene ring. The amino H atoms form intermolecular N—H⋯O hydrogen bonds with the O atoms of two adjacent molecules, resulting in 10-membered rings of graph-set motif R (2...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007237/ https://www.ncbi.nlm.nih.gov/pubmed/21588450 http://dx.doi.org/10.1107/S1600536810029508 |
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author | Ashiq, Uzma Jamal, Rifat Ara Arshad, Muhammad Nadeem Khan, Islam Ullah |
author_facet | Ashiq, Uzma Jamal, Rifat Ara Arshad, Muhammad Nadeem Khan, Islam Ullah |
author_sort | Ashiq, Uzma |
collection | PubMed |
description | In the title compound, C(7)H(7)ClN(2)O, the hydrazide group is inclined at a dihedral angle of 32.30 (11)° with respect to the benzene ring. The amino H atoms form intermolecular N—H⋯O hydrogen bonds with the O atoms of two adjacent molecules, resulting in 10-membered rings of graph-set motif R (2) (2)(10). The imino H atom is also involved in an intermolecular hydrogen bond with an amino N atom of a symmetry-related molecule, resulting in a zigzag chain along the b axis. The structure is further consolidated by an intramolecular N—H⋯O interaction, which results in a five-membered ring. |
format | Text |
id | pubmed-3007237 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072372010-12-30 3-Chlorobenzohydrazide Ashiq, Uzma Jamal, Rifat Ara Arshad, Muhammad Nadeem Khan, Islam Ullah Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(7)ClN(2)O, the hydrazide group is inclined at a dihedral angle of 32.30 (11)° with respect to the benzene ring. The amino H atoms form intermolecular N—H⋯O hydrogen bonds with the O atoms of two adjacent molecules, resulting in 10-membered rings of graph-set motif R (2) (2)(10). The imino H atom is also involved in an intermolecular hydrogen bond with an amino N atom of a symmetry-related molecule, resulting in a zigzag chain along the b axis. The structure is further consolidated by an intramolecular N—H⋯O interaction, which results in a five-membered ring. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007237/ /pubmed/21588450 http://dx.doi.org/10.1107/S1600536810029508 Text en © Ashiq et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ashiq, Uzma Jamal, Rifat Ara Arshad, Muhammad Nadeem Khan, Islam Ullah 3-Chlorobenzohydrazide |
title | 3-Chlorobenzohydrazide |
title_full | 3-Chlorobenzohydrazide |
title_fullStr | 3-Chlorobenzohydrazide |
title_full_unstemmed | 3-Chlorobenzohydrazide |
title_short | 3-Chlorobenzohydrazide |
title_sort | 3-chlorobenzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007237/ https://www.ncbi.nlm.nih.gov/pubmed/21588450 http://dx.doi.org/10.1107/S1600536810029508 |
work_keys_str_mv | AT ashiquzma 3chlorobenzohydrazide AT jamalrifatara 3chlorobenzohydrazide AT arshadmuhammadnadeem 3chlorobenzohydrazide AT khanislamullah 3chlorobenzohydrazide |