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3-Chloro­benzohydrazide

In the title compound, C(7)H(7)ClN(2)O, the hydrazide group is inclined at a dihedral angle of 32.30 (11)° with respect to the benzene ring. The amino H atoms form inter­molecular N—H⋯O hydrogen bonds with the O atoms of two adjacent mol­ecules, resulting in 10-membered rings of graph-set motif R (2...

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Detalles Bibliográficos
Autores principales: Ashiq, Uzma, Jamal, Rifat Ara, Arshad, Muhammad Nadeem, Khan, Islam Ullah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007237/
https://www.ncbi.nlm.nih.gov/pubmed/21588450
http://dx.doi.org/10.1107/S1600536810029508
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author Ashiq, Uzma
Jamal, Rifat Ara
Arshad, Muhammad Nadeem
Khan, Islam Ullah
author_facet Ashiq, Uzma
Jamal, Rifat Ara
Arshad, Muhammad Nadeem
Khan, Islam Ullah
author_sort Ashiq, Uzma
collection PubMed
description In the title compound, C(7)H(7)ClN(2)O, the hydrazide group is inclined at a dihedral angle of 32.30 (11)° with respect to the benzene ring. The amino H atoms form inter­molecular N—H⋯O hydrogen bonds with the O atoms of two adjacent mol­ecules, resulting in 10-membered rings of graph-set motif R (2) (2)(10). The imino H atom is also involved in an inter­molecular hydrogen bond with an amino N atom of a symmetry-related mol­ecule, resulting in a zigzag chain along the b axis. The structure is further consolidated by an intra­molecular N—H⋯O inter­action, which results in a five-membered ring.
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spelling pubmed-30072372010-12-30 3-Chloro­benzohydrazide Ashiq, Uzma Jamal, Rifat Ara Arshad, Muhammad Nadeem Khan, Islam Ullah Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(7)ClN(2)O, the hydrazide group is inclined at a dihedral angle of 32.30 (11)° with respect to the benzene ring. The amino H atoms form inter­molecular N—H⋯O hydrogen bonds with the O atoms of two adjacent mol­ecules, resulting in 10-membered rings of graph-set motif R (2) (2)(10). The imino H atom is also involved in an inter­molecular hydrogen bond with an amino N atom of a symmetry-related mol­ecule, resulting in a zigzag chain along the b axis. The structure is further consolidated by an intra­molecular N—H⋯O inter­action, which results in a five-membered ring. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007237/ /pubmed/21588450 http://dx.doi.org/10.1107/S1600536810029508 Text en © Ashiq et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ashiq, Uzma
Jamal, Rifat Ara
Arshad, Muhammad Nadeem
Khan, Islam Ullah
3-Chloro­benzohydrazide
title 3-Chloro­benzohydrazide
title_full 3-Chloro­benzohydrazide
title_fullStr 3-Chloro­benzohydrazide
title_full_unstemmed 3-Chloro­benzohydrazide
title_short 3-Chloro­benzohydrazide
title_sort 3-chloro­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007237/
https://www.ncbi.nlm.nih.gov/pubmed/21588450
http://dx.doi.org/10.1107/S1600536810029508
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