Hexaaqua­cobalt(II) 3,3′-dicarb­oxy­biphenyl-4,4′-dicarboxyl­ate

In the crystal structure of the title compound, [Co(H(2)O)(6)](C(16)H(8)O(8)), both the cation and anion are centrosymmetric. The Co cation displays a CoO(6) octa­hedral geometry formed by six water mol­ecules. In the anion, the two carboxyl groups are oriented at dihedral angles of 4.8 (5) and 10.4...

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Detalles Bibliográficos
Autores principales: Zhang, Yu-Hua, Han, Jin-Mei, Li, Zong-Ze
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007239/
https://www.ncbi.nlm.nih.gov/pubmed/21588087
http://dx.doi.org/10.1107/S1600536810028771
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author Zhang, Yu-Hua
Han, Jin-Mei
Li, Zong-Ze
author_facet Zhang, Yu-Hua
Han, Jin-Mei
Li, Zong-Ze
author_sort Zhang, Yu-Hua
collection PubMed
description In the crystal structure of the title compound, [Co(H(2)O)(6)](C(16)H(8)O(8)), both the cation and anion are centrosymmetric. The Co cation displays a CoO(6) octa­hedral geometry formed by six water mol­ecules. In the anion, the two carboxyl groups are oriented at dihedral angles of 4.8 (5) and 10.4 (7)° with respect to the benzene ring. Very strong O—H⋯O hydrogen bonds between the protonated and deprotonated carboxylate groups occur. Neighbouring cations and anions are connected through O—H⋯O hydrogen bonds into a three-dimensional supra­molecular structure.
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spelling pubmed-30072392010-12-30 Hexaaqua­cobalt(II) 3,3′-dicarb­oxy­biphenyl-4,4′-dicarboxyl­ate Zhang, Yu-Hua Han, Jin-Mei Li, Zong-Ze Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Co(H(2)O)(6)](C(16)H(8)O(8)), both the cation and anion are centrosymmetric. The Co cation displays a CoO(6) octa­hedral geometry formed by six water mol­ecules. In the anion, the two carboxyl groups are oriented at dihedral angles of 4.8 (5) and 10.4 (7)° with respect to the benzene ring. Very strong O—H⋯O hydrogen bonds between the protonated and deprotonated carboxylate groups occur. Neighbouring cations and anions are connected through O—H⋯O hydrogen bonds into a three-dimensional supra­molecular structure. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007239/ /pubmed/21588087 http://dx.doi.org/10.1107/S1600536810028771 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Yu-Hua
Han, Jin-Mei
Li, Zong-Ze
Hexaaqua­cobalt(II) 3,3′-dicarb­oxy­biphenyl-4,4′-dicarboxyl­ate
title Hexaaqua­cobalt(II) 3,3′-dicarb­oxy­biphenyl-4,4′-dicarboxyl­ate
title_full Hexaaqua­cobalt(II) 3,3′-dicarb­oxy­biphenyl-4,4′-dicarboxyl­ate
title_fullStr Hexaaqua­cobalt(II) 3,3′-dicarb­oxy­biphenyl-4,4′-dicarboxyl­ate
title_full_unstemmed Hexaaqua­cobalt(II) 3,3′-dicarb­oxy­biphenyl-4,4′-dicarboxyl­ate
title_short Hexaaqua­cobalt(II) 3,3′-dicarb­oxy­biphenyl-4,4′-dicarboxyl­ate
title_sort hexaaqua­cobalt(ii) 3,3′-dicarb­oxy­biphenyl-4,4′-dicarboxyl­ate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007239/
https://www.ncbi.nlm.nih.gov/pubmed/21588087
http://dx.doi.org/10.1107/S1600536810028771
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AT hanjinmei hexaaquacobaltii33dicarboxybiphenyl44dicarboxylate
AT lizongze hexaaquacobaltii33dicarboxybiphenyl44dicarboxylate

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