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4-Bromo-N (2),N (2),N (6),N (6)-tetraethylpyridine-2,6-dicarboxamide
The title compound, C(15)H(22)BrN(3)O(2), consists of a pyridine ring with a bromine atom in the para position and two diethylamide groups in the ortho positions of the ring. Despite the positions of the three substituents on the pyridine ring, the molecule does not exhibit either local or crystal...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007242/ https://www.ncbi.nlm.nih.gov/pubmed/21588413 http://dx.doi.org/10.1107/S1600536810028837 |
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author | de Lill, Daniel T. de Bettencourt-Dias, Ana |
author_facet | de Lill, Daniel T. de Bettencourt-Dias, Ana |
author_sort | de Lill, Daniel T. |
collection | PubMed |
description | The title compound, C(15)H(22)BrN(3)O(2), consists of a pyridine ring with a bromine atom in the para position and two diethylamide groups in the ortho positions of the ring. Despite the positions of the three substituents on the pyridine ring, the molecule does not exhibit either local or crystallographic twofold symmetry as the two diethylamido units exhibit significantly different N(py)—C—C—N(am) torsion angles of 46.3 (4) and 62.7 (4)° (py is pyridine and am is amine). Intermolecular C—H⋯O interactions support the packing. |
format | Text |
id | pubmed-3007242 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072422010-12-30 4-Bromo-N (2),N (2),N (6),N (6)-tetraethylpyridine-2,6-dicarboxamide de Lill, Daniel T. de Bettencourt-Dias, Ana Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(22)BrN(3)O(2), consists of a pyridine ring with a bromine atom in the para position and two diethylamide groups in the ortho positions of the ring. Despite the positions of the three substituents on the pyridine ring, the molecule does not exhibit either local or crystallographic twofold symmetry as the two diethylamido units exhibit significantly different N(py)—C—C—N(am) torsion angles of 46.3 (4) and 62.7 (4)° (py is pyridine and am is amine). Intermolecular C—H⋯O interactions support the packing. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007242/ /pubmed/21588413 http://dx.doi.org/10.1107/S1600536810028837 Text en © de Lill and de Bettencourt-Dias 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers de Lill, Daniel T. de Bettencourt-Dias, Ana 4-Bromo-N (2),N (2),N (6),N (6)-tetraethylpyridine-2,6-dicarboxamide |
title | 4-Bromo-N
(2),N
(2),N
(6),N
(6)-tetraethylpyridine-2,6-dicarboxamide |
title_full | 4-Bromo-N
(2),N
(2),N
(6),N
(6)-tetraethylpyridine-2,6-dicarboxamide |
title_fullStr | 4-Bromo-N
(2),N
(2),N
(6),N
(6)-tetraethylpyridine-2,6-dicarboxamide |
title_full_unstemmed | 4-Bromo-N
(2),N
(2),N
(6),N
(6)-tetraethylpyridine-2,6-dicarboxamide |
title_short | 4-Bromo-N
(2),N
(2),N
(6),N
(6)-tetraethylpyridine-2,6-dicarboxamide |
title_sort | 4-bromo-n
(2),n
(2),n
(6),n
(6)-tetraethylpyridine-2,6-dicarboxamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007242/ https://www.ncbi.nlm.nih.gov/pubmed/21588413 http://dx.doi.org/10.1107/S1600536810028837 |
work_keys_str_mv | AT delilldanielt 4bromon2n2n6n6tetraethylpyridine26dicarboxamide AT debettencourtdiasana 4bromon2n2n6n6tetraethylpyridine26dicarboxamide |