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4-Bromo-N (2),N (2),N (6),N (6)-tetra­ethyl­pyridine-2,6-dicarboxamide

The title compound, C(15)H(22)BrN(3)O(2), consists of a pyridine ring with a bromine atom in the para position and two diethyl­amide groups in the ortho positions of the ring. Despite the positions of the three substituents on the pyridine ring, the mol­ecule does not exhibit either local or crystal...

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Detalles Bibliográficos
Autores principales: de Lill, Daniel T., de Bettencourt-Dias, Ana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007242/
https://www.ncbi.nlm.nih.gov/pubmed/21588413
http://dx.doi.org/10.1107/S1600536810028837
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author de Lill, Daniel T.
de Bettencourt-Dias, Ana
author_facet de Lill, Daniel T.
de Bettencourt-Dias, Ana
author_sort de Lill, Daniel T.
collection PubMed
description The title compound, C(15)H(22)BrN(3)O(2), consists of a pyridine ring with a bromine atom in the para position and two diethyl­amide groups in the ortho positions of the ring. Despite the positions of the three substituents on the pyridine ring, the mol­ecule does not exhibit either local or crystallographic twofold symmetry as the two diethyl­amido units exhibit significantly different N(py)—C—C—N(am) torsion angles of 46.3 (4) and 62.7 (4)° (py is pyridine and am is amine). Inter­molecular C—H⋯O inter­actions support the packing.
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spelling pubmed-30072422010-12-30 4-Bromo-N (2),N (2),N (6),N (6)-tetra­ethyl­pyridine-2,6-dicarboxamide de Lill, Daniel T. de Bettencourt-Dias, Ana Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(22)BrN(3)O(2), consists of a pyridine ring with a bromine atom in the para position and two diethyl­amide groups in the ortho positions of the ring. Despite the positions of the three substituents on the pyridine ring, the mol­ecule does not exhibit either local or crystallographic twofold symmetry as the two diethyl­amido units exhibit significantly different N(py)—C—C—N(am) torsion angles of 46.3 (4) and 62.7 (4)° (py is pyridine and am is amine). Inter­molecular C—H⋯O inter­actions support the packing. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007242/ /pubmed/21588413 http://dx.doi.org/10.1107/S1600536810028837 Text en © de Lill and de Bettencourt-Dias 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
de Lill, Daniel T.
de Bettencourt-Dias, Ana
4-Bromo-N (2),N (2),N (6),N (6)-tetra­ethyl­pyridine-2,6-dicarboxamide
title 4-Bromo-N (2),N (2),N (6),N (6)-tetra­ethyl­pyridine-2,6-dicarboxamide
title_full 4-Bromo-N (2),N (2),N (6),N (6)-tetra­ethyl­pyridine-2,6-dicarboxamide
title_fullStr 4-Bromo-N (2),N (2),N (6),N (6)-tetra­ethyl­pyridine-2,6-dicarboxamide
title_full_unstemmed 4-Bromo-N (2),N (2),N (6),N (6)-tetra­ethyl­pyridine-2,6-dicarboxamide
title_short 4-Bromo-N (2),N (2),N (6),N (6)-tetra­ethyl­pyridine-2,6-dicarboxamide
title_sort 4-bromo-n (2),n (2),n (6),n (6)-tetra­ethyl­pyridine-2,6-dicarboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007242/
https://www.ncbi.nlm.nih.gov/pubmed/21588413
http://dx.doi.org/10.1107/S1600536810028837
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