Bis[N,N-bis­(diphenyl­phosphan­yl)cyclo­hexyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluorido­phosphate) dichloro­methane disolvate

In the title compound, [Pt(C(30)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), the four-coordinated Pt(II) atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclo­hexyl ring and one of the phenyl rings display 0....

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Detalles Bibliográficos
Autores principales: Engelbrecht, Ilana, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007244/
https://www.ncbi.nlm.nih.gov/pubmed/21588214
http://dx.doi.org/10.1107/S1600536810028795
Descripción
Sumario:In the title compound, [Pt(C(30)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), the four-coordinated Pt(II) atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclo­hexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloro­methane solvent mol­ecule displays 0.526 (4):0.474 (4) positional disorder. C—H⋯F hydrogen bonds stabilize the crystal packing.

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