Bis[N,N-bis­(diphenyl­phosphan­yl)cyclo­hexyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluorido­phosphate) dichloro­methane disolvate

In the title compound, [Pt(C(30)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), the four-coordinated Pt(II) atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclo­hexyl ring and one of the phenyl rings display 0....

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Detalles Bibliográficos
Autores principales: Engelbrecht, Ilana, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007244/
https://www.ncbi.nlm.nih.gov/pubmed/21588214
http://dx.doi.org/10.1107/S1600536810028795
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author Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
author_facet Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
author_sort Engelbrecht, Ilana
collection PubMed
description In the title compound, [Pt(C(30)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), the four-coordinated Pt(II) atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclo­hexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloro­methane solvent mol­ecule displays 0.526 (4):0.474 (4) positional disorder. C—H⋯F hydrogen bonds stabilize the crystal packing.
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spelling pubmed-30072442010-12-30 Bis[N,N-bis­(diphenyl­phosphan­yl)cyclo­hexyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluorido­phosphate) dichloro­methane disolvate Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pt(C(30)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), the four-coordinated Pt(II) atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclo­hexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloro­methane solvent mol­ecule displays 0.526 (4):0.474 (4) positional disorder. C—H⋯F hydrogen bonds stabilize the crystal packing. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007244/ /pubmed/21588214 http://dx.doi.org/10.1107/S1600536810028795 Text en © Engelbrecht et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
Bis[N,N-bis­(diphenyl­phosphan­yl)cyclo­hexyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluorido­phosphate) dichloro­methane disolvate
title Bis[N,N-bis­(diphenyl­phosphan­yl)cyclo­hexyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluorido­phosphate) dichloro­methane disolvate
title_full Bis[N,N-bis­(diphenyl­phosphan­yl)cyclo­hexyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluorido­phosphate) dichloro­methane disolvate
title_fullStr Bis[N,N-bis­(diphenyl­phosphan­yl)cyclo­hexyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluorido­phosphate) dichloro­methane disolvate
title_full_unstemmed Bis[N,N-bis­(diphenyl­phosphan­yl)cyclo­hexyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluorido­phosphate) dichloro­methane disolvate
title_short Bis[N,N-bis­(diphenyl­phosphan­yl)cyclo­hexyl­amine-κ(2) P,P′]platinum(II) bis­(hexa­fluorido­phosphate) dichloro­methane disolvate
title_sort bis[n,n-bis­(diphenyl­phosphan­yl)cyclo­hexyl­amine-κ(2) p,p′]platinum(ii) bis­(hexa­fluorido­phosphate) dichloro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007244/
https://www.ncbi.nlm.nih.gov/pubmed/21588214
http://dx.doi.org/10.1107/S1600536810028795
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AT visserhendrikg bisnnbisdiphenylphosphanylcyclohexylaminek2ppplatinumiibishexafluoridophosphatedichloromethanedisolvate
AT roodtandreas bisnnbisdiphenylphosphanylcyclohexylaminek2ppplatinumiibishexafluoridophosphatedichloromethanedisolvate

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