Cargando…
(1,4,7,10-Tetraazacyclododecane-κ(4) N (1),N (4),N (7),N (10))(tetraoxidomolybdato-κO)copper(II) monohydrate
In the title compound, [CuMoO(4)(C(8)H(20)N(4))]·H(2)O, the Cu(II) atom is coordinated by four N atoms of the 1,4,7,10-tetraazacyclododecane (cyclen) ligand and one O atom of the molybdate unit in a distorted square-pyramidal environment. The water molecules are linked to the complex unit to for...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007245/ https://www.ncbi.nlm.nih.gov/pubmed/21588138 http://dx.doi.org/10.1107/S1600536810026000 |
_version_ | 1782194310341459968 |
---|---|
author | Rohde, Dorothea Merzweiler, Kurt |
author_facet | Rohde, Dorothea Merzweiler, Kurt |
author_sort | Rohde, Dorothea |
collection | PubMed |
description | In the title compound, [CuMoO(4)(C(8)H(20)N(4))]·H(2)O, the Cu(II) atom is coordinated by four N atoms of the 1,4,7,10-tetraazacyclododecane (cyclen) ligand and one O atom of the molybdate unit in a distorted square-pyramidal environment. The water molecules are linked to the complex unit to form centrosymmetric dimers [R (4) (4)(12) and R (4) (4)(16)] and discrete D (3) (2)(9), D (3) (3)(11) and D (3) (3)(13) chains by O—H⋯O and N—H⋯O interactions. Additionally, the complex molecules are linked into C (4) (4)(18) chain motifs by N—H⋯O interactions. As a result [(cyclen)CuMoO(4)] units and water molecules are linked to layers that are oriented parallel to the ac plane. The stacking of the layers in the b-axis direction is supported by weak C—H⋯O hydrogen bridges. |
format | Text |
id | pubmed-3007245 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072452010-12-30 (1,4,7,10-Tetraazacyclododecane-κ(4) N (1),N (4),N (7),N (10))(tetraoxidomolybdato-κO)copper(II) monohydrate Rohde, Dorothea Merzweiler, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuMoO(4)(C(8)H(20)N(4))]·H(2)O, the Cu(II) atom is coordinated by four N atoms of the 1,4,7,10-tetraazacyclododecane (cyclen) ligand and one O atom of the molybdate unit in a distorted square-pyramidal environment. The water molecules are linked to the complex unit to form centrosymmetric dimers [R (4) (4)(12) and R (4) (4)(16)] and discrete D (3) (2)(9), D (3) (3)(11) and D (3) (3)(13) chains by O—H⋯O and N—H⋯O interactions. Additionally, the complex molecules are linked into C (4) (4)(18) chain motifs by N—H⋯O interactions. As a result [(cyclen)CuMoO(4)] units and water molecules are linked to layers that are oriented parallel to the ac plane. The stacking of the layers in the b-axis direction is supported by weak C—H⋯O hydrogen bridges. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007245/ /pubmed/21588138 http://dx.doi.org/10.1107/S1600536810026000 Text en © Rohde and Merzweiler 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Rohde, Dorothea Merzweiler, Kurt (1,4,7,10-Tetraazacyclododecane-κ(4) N (1),N (4),N (7),N (10))(tetraoxidomolybdato-κO)copper(II) monohydrate |
title | (1,4,7,10-Tetraazacyclododecane-κ(4)
N
(1),N
(4),N
(7),N
(10))(tetraoxidomolybdato-κO)copper(II) monohydrate |
title_full | (1,4,7,10-Tetraazacyclododecane-κ(4)
N
(1),N
(4),N
(7),N
(10))(tetraoxidomolybdato-κO)copper(II) monohydrate |
title_fullStr | (1,4,7,10-Tetraazacyclododecane-κ(4)
N
(1),N
(4),N
(7),N
(10))(tetraoxidomolybdato-κO)copper(II) monohydrate |
title_full_unstemmed | (1,4,7,10-Tetraazacyclododecane-κ(4)
N
(1),N
(4),N
(7),N
(10))(tetraoxidomolybdato-κO)copper(II) monohydrate |
title_short | (1,4,7,10-Tetraazacyclododecane-κ(4)
N
(1),N
(4),N
(7),N
(10))(tetraoxidomolybdato-κO)copper(II) monohydrate |
title_sort | (1,4,7,10-tetraazacyclododecane-κ(4)
n
(1),n
(4),n
(7),n
(10))(tetraoxidomolybdato-κo)copper(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007245/ https://www.ncbi.nlm.nih.gov/pubmed/21588138 http://dx.doi.org/10.1107/S1600536810026000 |
work_keys_str_mv | AT rohdedorothea 14710tetraazacyclododecanek4n1n4n7n10tetraoxidomolybdatokocopperiimonohydrate AT merzweilerkurt 14710tetraazacyclododecanek4n1n4n7n10tetraoxidomolybdatokocopperiimonohydrate |