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(1,4,7,10-Tetra­aza­cyclo­dodecane-κ(4) N (1),N (4),N (7),N (10))(tetra­oxidomolybdato-κO)copper(II) monohydrate

In the title compound, [CuMoO(4)(C(8)H(20)N(4))]·H(2)O, the Cu(II) atom is coordinated by four N atoms of the 1,4,7,10-tetra­aza­cyclo­dodecane (cyclen) ligand and one O atom of the molybdate unit in a distorted square-pyramidal environment. The water mol­ecules are linked to the complex unit to for...

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Autores principales: Rohde, Dorothea, Merzweiler, Kurt
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007245/
https://www.ncbi.nlm.nih.gov/pubmed/21588138
http://dx.doi.org/10.1107/S1600536810026000
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author Rohde, Dorothea
Merzweiler, Kurt
author_facet Rohde, Dorothea
Merzweiler, Kurt
author_sort Rohde, Dorothea
collection PubMed
description In the title compound, [CuMoO(4)(C(8)H(20)N(4))]·H(2)O, the Cu(II) atom is coordinated by four N atoms of the 1,4,7,10-tetra­aza­cyclo­dodecane (cyclen) ligand and one O atom of the molybdate unit in a distorted square-pyramidal environment. The water mol­ecules are linked to the complex unit to form centrosymmetric dimers [R (4) (4)(12) and R (4) (4)(16)] and discrete D (3) (2)(9), D (3) (3)(11) and D (3) (3)(13) chains by O—H⋯O and N—H⋯O inter­actions. Additionally, the complex mol­ecules are linked into C (4) (4)(18) chain motifs by N—H⋯O inter­actions. As a result [(cyclen)CuMoO(4)] units and water molecules are linked to layers that are oriented parallel to the ac plane. The stacking of the layers in the b-axis direction is supported by weak C—H⋯O hydrogen bridges.
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spelling pubmed-30072452010-12-30 (1,4,7,10-Tetra­aza­cyclo­dodecane-κ(4) N (1),N (4),N (7),N (10))(tetra­oxidomolybdato-κO)copper(II) monohydrate Rohde, Dorothea Merzweiler, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuMoO(4)(C(8)H(20)N(4))]·H(2)O, the Cu(II) atom is coordinated by four N atoms of the 1,4,7,10-tetra­aza­cyclo­dodecane (cyclen) ligand and one O atom of the molybdate unit in a distorted square-pyramidal environment. The water mol­ecules are linked to the complex unit to form centrosymmetric dimers [R (4) (4)(12) and R (4) (4)(16)] and discrete D (3) (2)(9), D (3) (3)(11) and D (3) (3)(13) chains by O—H⋯O and N—H⋯O inter­actions. Additionally, the complex mol­ecules are linked into C (4) (4)(18) chain motifs by N—H⋯O inter­actions. As a result [(cyclen)CuMoO(4)] units and water molecules are linked to layers that are oriented parallel to the ac plane. The stacking of the layers in the b-axis direction is supported by weak C—H⋯O hydrogen bridges. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007245/ /pubmed/21588138 http://dx.doi.org/10.1107/S1600536810026000 Text en © Rohde and Merzweiler 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rohde, Dorothea
Merzweiler, Kurt
(1,4,7,10-Tetra­aza­cyclo­dodecane-κ(4) N (1),N (4),N (7),N (10))(tetra­oxidomolybdato-κO)copper(II) monohydrate
title (1,4,7,10-Tetra­aza­cyclo­dodecane-κ(4) N (1),N (4),N (7),N (10))(tetra­oxidomolybdato-κO)copper(II) monohydrate
title_full (1,4,7,10-Tetra­aza­cyclo­dodecane-κ(4) N (1),N (4),N (7),N (10))(tetra­oxidomolybdato-κO)copper(II) monohydrate
title_fullStr (1,4,7,10-Tetra­aza­cyclo­dodecane-κ(4) N (1),N (4),N (7),N (10))(tetra­oxidomolybdato-κO)copper(II) monohydrate
title_full_unstemmed (1,4,7,10-Tetra­aza­cyclo­dodecane-κ(4) N (1),N (4),N (7),N (10))(tetra­oxidomolybdato-κO)copper(II) monohydrate
title_short (1,4,7,10-Tetra­aza­cyclo­dodecane-κ(4) N (1),N (4),N (7),N (10))(tetra­oxidomolybdato-κO)copper(II) monohydrate
title_sort (1,4,7,10-tetra­aza­cyclo­dodecane-κ(4) n (1),n (4),n (7),n (10))(tetra­oxidomolybdato-κo)copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007245/
https://www.ncbi.nlm.nih.gov/pubmed/21588138
http://dx.doi.org/10.1107/S1600536810026000
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