N-(4-Chloro­phen­yl)-4-methyl­pyridin-2-amine

In the title compound, C(12)H(11)ClN(2), the dihedral angle between the benzene and pyridyl rings is 48.03 (8)°. Twists are also evident in the mol­ecule, in particular about the N(a)–C(b) (a = amine and b = benzene) bond [C—N—C—C = −144.79 (18)°]. In the crystal, inversion dimers linked by pairs of...

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Autores principales: Fairuz, Zainal A., Aiyub, Zaharah, Abdullah, Zanariah, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007248/
https://www.ncbi.nlm.nih.gov/pubmed/21588463
http://dx.doi.org/10.1107/S1600536810030138
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author Fairuz, Zainal A.
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Fairuz, Zainal A.
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Fairuz, Zainal A.
collection PubMed
description In the title compound, C(12)H(11)ClN(2), the dihedral angle between the benzene and pyridyl rings is 48.03 (8)°. Twists are also evident in the mol­ecule, in particular about the N(a)–C(b) (a = amine and b = benzene) bond [C—N—C—C = −144.79 (18)°]. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds result in the formation of eight-membered {⋯NCNH}(2) synthons [or R (2) (2)(8) loops].
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spelling pubmed-30072482010-12-30 N-(4-Chloro­phen­yl)-4-methyl­pyridin-2-amine Fairuz, Zainal A. Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(11)ClN(2), the dihedral angle between the benzene and pyridyl rings is 48.03 (8)°. Twists are also evident in the mol­ecule, in particular about the N(a)–C(b) (a = amine and b = benzene) bond [C—N—C—C = −144.79 (18)°]. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds result in the formation of eight-membered {⋯NCNH}(2) synthons [or R (2) (2)(8) loops]. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007248/ /pubmed/21588463 http://dx.doi.org/10.1107/S1600536810030138 Text en © Fairuz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fairuz, Zainal A.
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
N-(4-Chloro­phen­yl)-4-methyl­pyridin-2-amine
title N-(4-Chloro­phen­yl)-4-methyl­pyridin-2-amine
title_full N-(4-Chloro­phen­yl)-4-methyl­pyridin-2-amine
title_fullStr N-(4-Chloro­phen­yl)-4-methyl­pyridin-2-amine
title_full_unstemmed N-(4-Chloro­phen­yl)-4-methyl­pyridin-2-amine
title_short N-(4-Chloro­phen­yl)-4-methyl­pyridin-2-amine
title_sort n-(4-chloro­phen­yl)-4-methyl­pyridin-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007248/
https://www.ncbi.nlm.nih.gov/pubmed/21588463
http://dx.doi.org/10.1107/S1600536810030138
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AT ngseikweng n4chlorophenyl4methylpyridin2amine
AT tiekinkedwardrt n4chlorophenyl4methylpyridin2amine

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