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N′-[Bis(benzyl­sulfan­yl)methyl­idene]-4-meth­oxy­benzohydrazide

In the title compound, C(23)H(22)N(2)O(2)S(2), the dihedral angles between the 4-meth­oxy-substituted phenyl ring and the other two phenyl rings are 84.4 (4) and 77.7 (1)°, respectively, while the dihedral angle between the two phenyl rings is 57.5 (2)°. The amino group is not involved in an N—H hyd...

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Autores principales: Jasinski, Jerry P., Butcher, Ray J., Kushawaha, S. K., Bharty, M. K., Singh, N. K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007250/
https://www.ncbi.nlm.nih.gov/pubmed/21588233
http://dx.doi.org/10.1107/S1600536810025389
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author Jasinski, Jerry P.
Butcher, Ray J.
Kushawaha, S. K.
Bharty, M. K.
Singh, N. K.
author_facet Jasinski, Jerry P.
Butcher, Ray J.
Kushawaha, S. K.
Bharty, M. K.
Singh, N. K.
author_sort Jasinski, Jerry P.
collection PubMed
description In the title compound, C(23)H(22)N(2)O(2)S(2), the dihedral angles between the 4-meth­oxy-substituted phenyl ring and the other two phenyl rings are 84.4 (4) and 77.7 (1)°, respectively, while the dihedral angle between the two phenyl rings is 57.5 (2)°. The amino group is not involved in an N—H hydrogen bond. The crystal packing is established by inter­molecular C—H⋯O packing inter­actions involving a relatively rare weak three-center hydrogen bond between the keto O atom and H atoms of the two nearby phenyl rings, which link the mol­ecules into chains running along the a axis. Additional weak inter­molecular hydrogen-bond inter­actions between the 4-meth­oxy O atom and one of the phenyl rings and provide added stability to the crystal packing.
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spelling pubmed-30072502010-12-30 N′-[Bis(benzyl­sulfan­yl)methyl­idene]-4-meth­oxy­benzohydrazide Jasinski, Jerry P. Butcher, Ray J. Kushawaha, S. K. Bharty, M. K. Singh, N. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(22)N(2)O(2)S(2), the dihedral angles between the 4-meth­oxy-substituted phenyl ring and the other two phenyl rings are 84.4 (4) and 77.7 (1)°, respectively, while the dihedral angle between the two phenyl rings is 57.5 (2)°. The amino group is not involved in an N—H hydrogen bond. The crystal packing is established by inter­molecular C—H⋯O packing inter­actions involving a relatively rare weak three-center hydrogen bond between the keto O atom and H atoms of the two nearby phenyl rings, which link the mol­ecules into chains running along the a axis. Additional weak inter­molecular hydrogen-bond inter­actions between the 4-meth­oxy O atom and one of the phenyl rings and provide added stability to the crystal packing. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007250/ /pubmed/21588233 http://dx.doi.org/10.1107/S1600536810025389 Text en © Jasinski et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jasinski, Jerry P.
Butcher, Ray J.
Kushawaha, S. K.
Bharty, M. K.
Singh, N. K.
N′-[Bis(benzyl­sulfan­yl)methyl­idene]-4-meth­oxy­benzohydrazide
title N′-[Bis(benzyl­sulfan­yl)methyl­idene]-4-meth­oxy­benzohydrazide
title_full N′-[Bis(benzyl­sulfan­yl)methyl­idene]-4-meth­oxy­benzohydrazide
title_fullStr N′-[Bis(benzyl­sulfan­yl)methyl­idene]-4-meth­oxy­benzohydrazide
title_full_unstemmed N′-[Bis(benzyl­sulfan­yl)methyl­idene]-4-meth­oxy­benzohydrazide
title_short N′-[Bis(benzyl­sulfan­yl)methyl­idene]-4-meth­oxy­benzohydrazide
title_sort n′-[bis(benzyl­sulfan­yl)methyl­idene]-4-meth­oxy­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007250/
https://www.ncbi.nlm.nih.gov/pubmed/21588233
http://dx.doi.org/10.1107/S1600536810025389
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