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N′-[Bis(benzylsulfanyl)methylidene]-4-methoxybenzohydrazide
In the title compound, C(23)H(22)N(2)O(2)S(2), the dihedral angles between the 4-methoxy-substituted phenyl ring and the other two phenyl rings are 84.4 (4) and 77.7 (1)°, respectively, while the dihedral angle between the two phenyl rings is 57.5 (2)°. The amino group is not involved in an N—H hyd...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007250/ https://www.ncbi.nlm.nih.gov/pubmed/21588233 http://dx.doi.org/10.1107/S1600536810025389 |
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author | Jasinski, Jerry P. Butcher, Ray J. Kushawaha, S. K. Bharty, M. K. Singh, N. K. |
author_facet | Jasinski, Jerry P. Butcher, Ray J. Kushawaha, S. K. Bharty, M. K. Singh, N. K. |
author_sort | Jasinski, Jerry P. |
collection | PubMed |
description | In the title compound, C(23)H(22)N(2)O(2)S(2), the dihedral angles between the 4-methoxy-substituted phenyl ring and the other two phenyl rings are 84.4 (4) and 77.7 (1)°, respectively, while the dihedral angle between the two phenyl rings is 57.5 (2)°. The amino group is not involved in an N—H hydrogen bond. The crystal packing is established by intermolecular C—H⋯O packing interactions involving a relatively rare weak three-center hydrogen bond between the keto O atom and H atoms of the two nearby phenyl rings, which link the molecules into chains running along the a axis. Additional weak intermolecular hydrogen-bond interactions between the 4-methoxy O atom and one of the phenyl rings and provide added stability to the crystal packing. |
format | Text |
id | pubmed-3007250 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072502010-12-30 N′-[Bis(benzylsulfanyl)methylidene]-4-methoxybenzohydrazide Jasinski, Jerry P. Butcher, Ray J. Kushawaha, S. K. Bharty, M. K. Singh, N. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(22)N(2)O(2)S(2), the dihedral angles between the 4-methoxy-substituted phenyl ring and the other two phenyl rings are 84.4 (4) and 77.7 (1)°, respectively, while the dihedral angle between the two phenyl rings is 57.5 (2)°. The amino group is not involved in an N—H hydrogen bond. The crystal packing is established by intermolecular C—H⋯O packing interactions involving a relatively rare weak three-center hydrogen bond between the keto O atom and H atoms of the two nearby phenyl rings, which link the molecules into chains running along the a axis. Additional weak intermolecular hydrogen-bond interactions between the 4-methoxy O atom and one of the phenyl rings and provide added stability to the crystal packing. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007250/ /pubmed/21588233 http://dx.doi.org/10.1107/S1600536810025389 Text en © Jasinski et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jasinski, Jerry P. Butcher, Ray J. Kushawaha, S. K. Bharty, M. K. Singh, N. K. N′-[Bis(benzylsulfanyl)methylidene]-4-methoxybenzohydrazide |
title |
N′-[Bis(benzylsulfanyl)methylidene]-4-methoxybenzohydrazide |
title_full |
N′-[Bis(benzylsulfanyl)methylidene]-4-methoxybenzohydrazide |
title_fullStr |
N′-[Bis(benzylsulfanyl)methylidene]-4-methoxybenzohydrazide |
title_full_unstemmed |
N′-[Bis(benzylsulfanyl)methylidene]-4-methoxybenzohydrazide |
title_short |
N′-[Bis(benzylsulfanyl)methylidene]-4-methoxybenzohydrazide |
title_sort | n′-[bis(benzylsulfanyl)methylidene]-4-methoxybenzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007250/ https://www.ncbi.nlm.nih.gov/pubmed/21588233 http://dx.doi.org/10.1107/S1600536810025389 |
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