Amino­(5-{2-[amino­(iminio)meth­yl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate

The reaction of aqueous solutions of amino­guanidine hydrogennitrate and acetyl­acetone produces the title pyrazole salt, C(7)H(18)N(8) (2+)·2NO(3) (−). The crystal structure is stabilized by a complex N—H⋯O hydrogen-bonding network. The difference in the engagement of the two nitrate anions in hydr...

Descripción completa

Detalles Bibliográficos
Autores principales: Novaković, Sladjana B., Lalović, Mirjana, Divjaković, Vladimir, Vojinović-Ješić, Ljiljana S., Češljević, Valerija I.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007255/
https://www.ncbi.nlm.nih.gov/pubmed/21588248
http://dx.doi.org/10.1107/S1600536810025006
_version_ 1782194312748990464
author Novaković, Sladjana B.
Lalović, Mirjana
Divjaković, Vladimir
Vojinović-Ješić, Ljiljana S.
Češljević, Valerija I.
author_facet Novaković, Sladjana B.
Lalović, Mirjana
Divjaković, Vladimir
Vojinović-Ješić, Ljiljana S.
Češljević, Valerija I.
author_sort Novaković, Sladjana B.
collection PubMed
description The reaction of aqueous solutions of amino­guanidine hydrogennitrate and acetyl­acetone produces the title pyrazole salt, C(7)H(18)N(8) (2+)·2NO(3) (−). The crystal structure is stabilized by a complex N—H⋯O hydrogen-bonding network. The difference in the engagement of the two nitrate anions in hydrogen bonding is reflected in the variation of the corresponding N—O bond lengths.
format Text
id pubmed-3007255
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30072552010-12-30 Amino­(5-{2-[amino­(iminio)meth­yl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate Novaković, Sladjana B. Lalović, Mirjana Divjaković, Vladimir Vojinović-Ješić, Ljiljana S. Češljević, Valerija I. Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of aqueous solutions of amino­guanidine hydrogennitrate and acetyl­acetone produces the title pyrazole salt, C(7)H(18)N(8) (2+)·2NO(3) (−). The crystal structure is stabilized by a complex N—H⋯O hydrogen-bonding network. The difference in the engagement of the two nitrate anions in hydrogen bonding is reflected in the variation of the corresponding N—O bond lengths. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007255/ /pubmed/21588248 http://dx.doi.org/10.1107/S1600536810025006 Text en © Novaković et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Novaković, Sladjana B.
Lalović, Mirjana
Divjaković, Vladimir
Vojinović-Ješić, Ljiljana S.
Češljević, Valerija I.
Amino­(5-{2-[amino­(iminio)meth­yl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate
title Amino­(5-{2-[amino­(iminio)meth­yl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate
title_full Amino­(5-{2-[amino­(iminio)meth­yl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate
title_fullStr Amino­(5-{2-[amino­(iminio)meth­yl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate
title_full_unstemmed Amino­(5-{2-[amino­(iminio)meth­yl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate
title_short Amino­(5-{2-[amino­(iminio)meth­yl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate
title_sort amino­(5-{2-[amino­(iminio)meth­yl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1h-pyrazol-1-yl)methaniminium dinitrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007255/
https://www.ncbi.nlm.nih.gov/pubmed/21588248
http://dx.doi.org/10.1107/S1600536810025006
work_keys_str_mv AT novakovicsladjanab amino52aminoiminiomethylhydrazin1yl35dimethyl45dihydro1hpyrazol1ylmethaniminiumdinitrate
AT lalovicmirjana amino52aminoiminiomethylhydrazin1yl35dimethyl45dihydro1hpyrazol1ylmethaniminiumdinitrate
AT divjakovicvladimir amino52aminoiminiomethylhydrazin1yl35dimethyl45dihydro1hpyrazol1ylmethaniminiumdinitrate
AT vojinovicjesicljiljanas amino52aminoiminiomethylhydrazin1yl35dimethyl45dihydro1hpyrazol1ylmethaniminiumdinitrate
AT cesljevicvalerijai amino52aminoiminiomethylhydrazin1yl35dimethyl45dihydro1hpyrazol1ylmethaniminiumdinitrate

Ejemplares similares