16-[(E)-Benzyl­idene]-2-hy­droxy-12,13-diphenyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione

In the title compound, C(35)H(28)N(2)O(3), an intra­molecular O—H⋯N hydrogen bonds generates a five-membered ring, producing an S(5) ring motif. The piperidone ring adopts a half-chair conformation and the two pyrrolidine rings adopt an envelope conformation. The dihedral angles formed between adjac...

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Autores principales: Kumar, Raju Suresh, Osman, Hasnah, Ali, Mohamed Ashraf, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007256/
https://www.ncbi.nlm.nih.gov/pubmed/21588383
http://dx.doi.org/10.1107/S1600536810028345
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author Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Kumar, Raju Suresh
collection PubMed
description In the title compound, C(35)H(28)N(2)O(3), an intra­molecular O—H⋯N hydrogen bonds generates a five-membered ring, producing an S(5) ring motif. The piperidone ring adopts a half-chair conformation and the two pyrrolidine rings adopt an envelope conformation. The dihedral angles formed between adjacent benzene rings are 74.39 (5) and 37.70 (6)°. In the crystal crystal, inter­molecular C—H⋯O hydrogen bonds link mol­ecules into dimers, which are further inter­connected into two-dimensional networks parallel to the ac plane by inter­molecular C—H⋯O hydrogen bonds. The crystal structure is consolidated by weak C—H⋯π inter­actions.
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spelling pubmed-30072562010-12-30 16-[(E)-Benzyl­idene]-2-hy­droxy-12,13-diphenyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione Kumar, Raju Suresh Osman, Hasnah Ali, Mohamed Ashraf Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(35)H(28)N(2)O(3), an intra­molecular O—H⋯N hydrogen bonds generates a five-membered ring, producing an S(5) ring motif. The piperidone ring adopts a half-chair conformation and the two pyrrolidine rings adopt an envelope conformation. The dihedral angles formed between adjacent benzene rings are 74.39 (5) and 37.70 (6)°. In the crystal crystal, inter­molecular C—H⋯O hydrogen bonds link mol­ecules into dimers, which are further inter­connected into two-dimensional networks parallel to the ac plane by inter­molecular C—H⋯O hydrogen bonds. The crystal structure is consolidated by weak C—H⋯π inter­actions. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007256/ /pubmed/21588383 http://dx.doi.org/10.1107/S1600536810028345 Text en © Kumar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Goh, Jia Hao
Fun, Hoong-Kun
16-[(E)-Benzyl­idene]-2-hy­droxy-12,13-diphenyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title 16-[(E)-Benzyl­idene]-2-hy­droxy-12,13-diphenyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_full 16-[(E)-Benzyl­idene]-2-hy­droxy-12,13-diphenyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_fullStr 16-[(E)-Benzyl­idene]-2-hy­droxy-12,13-diphenyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_full_unstemmed 16-[(E)-Benzyl­idene]-2-hy­droxy-12,13-diphenyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_short 16-[(E)-Benzyl­idene]-2-hy­droxy-12,13-diphenyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
title_sort 16-[(e)-benzyl­idene]-2-hy­droxy-12,13-diphenyl-1,11-diaza­penta­cyclo­[12.3.1.0(2,10).0(3,8).0(10,14)]octa­deca-3(8),4,6-triene-9,15-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007256/
https://www.ncbi.nlm.nih.gov/pubmed/21588383
http://dx.doi.org/10.1107/S1600536810028345
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