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1-(2,4-Dinitro­phen­yl)-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazine

In the title compound, C(14)H(14)N(4)O(4), the dihedral angle between the benzene rings is 10.42 (8)°. The nitro groups make dihedral angles of 5.3 (2) and 6.47 (15)° with their parent ring and are oriented at 11.2 (3)° with respect to each other. An intra­molecular N—H⋯O hydrogen bond completes an...

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Detalles Bibliográficos
Autores principales: Danish, M., Hamid, Masood, Tahir, M. Nawaz, Ahmad, Nazir, Ghafoor, Sabiha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007257/
https://www.ncbi.nlm.nih.gov/pubmed/21588393
http://dx.doi.org/10.1107/S1600536810028680
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author Danish, M.
Hamid, Masood
Tahir, M. Nawaz
Ahmad, Nazir
Ghafoor, Sabiha
author_facet Danish, M.
Hamid, Masood
Tahir, M. Nawaz
Ahmad, Nazir
Ghafoor, Sabiha
author_sort Danish, M.
collection PubMed
description In the title compound, C(14)H(14)N(4)O(4), the dihedral angle between the benzene rings is 10.42 (8)°. The nitro groups make dihedral angles of 5.3 (2) and 6.47 (15)° with their parent ring and are oriented at 11.2 (3)° with respect to each other. An intra­molecular N—H⋯O hydrogen bond completes an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O inter­actions, thus forming (010) chains in which R (2) (2)(13) ring motifs are present. There also exist aromatic π–π stacking inter­actions [centroid–centroid separation = 3.7046 (9) Å].
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spelling pubmed-30072572010-12-30 1-(2,4-Dinitro­phen­yl)-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazine Danish, M. Hamid, Masood Tahir, M. Nawaz Ahmad, Nazir Ghafoor, Sabiha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)N(4)O(4), the dihedral angle between the benzene rings is 10.42 (8)°. The nitro groups make dihedral angles of 5.3 (2) and 6.47 (15)° with their parent ring and are oriented at 11.2 (3)° with respect to each other. An intra­molecular N—H⋯O hydrogen bond completes an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O inter­actions, thus forming (010) chains in which R (2) (2)(13) ring motifs are present. There also exist aromatic π–π stacking inter­actions [centroid–centroid separation = 3.7046 (9) Å]. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007257/ /pubmed/21588393 http://dx.doi.org/10.1107/S1600536810028680 Text en © Danish et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Danish, M.
Hamid, Masood
Tahir, M. Nawaz
Ahmad, Nazir
Ghafoor, Sabiha
1-(2,4-Dinitro­phen­yl)-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazine
title 1-(2,4-Dinitro­phen­yl)-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazine
title_full 1-(2,4-Dinitro­phen­yl)-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazine
title_fullStr 1-(2,4-Dinitro­phen­yl)-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazine
title_full_unstemmed 1-(2,4-Dinitro­phen­yl)-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazine
title_short 1-(2,4-Dinitro­phen­yl)-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazine
title_sort 1-(2,4-dinitro­phen­yl)-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007257/
https://www.ncbi.nlm.nih.gov/pubmed/21588393
http://dx.doi.org/10.1107/S1600536810028680
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