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1-(2,4-Dinitrophenyl)-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazine
In the title compound, C(14)H(14)N(4)O(4), the dihedral angle between the benzene rings is 10.42 (8)°. The nitro groups make dihedral angles of 5.3 (2) and 6.47 (15)° with their parent ring and are oriented at 11.2 (3)° with respect to each other. An intramolecular N—H⋯O hydrogen bond completes an...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007257/ https://www.ncbi.nlm.nih.gov/pubmed/21588393 http://dx.doi.org/10.1107/S1600536810028680 |
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author | Danish, M. Hamid, Masood Tahir, M. Nawaz Ahmad, Nazir Ghafoor, Sabiha |
author_facet | Danish, M. Hamid, Masood Tahir, M. Nawaz Ahmad, Nazir Ghafoor, Sabiha |
author_sort | Danish, M. |
collection | PubMed |
description | In the title compound, C(14)H(14)N(4)O(4), the dihedral angle between the benzene rings is 10.42 (8)°. The nitro groups make dihedral angles of 5.3 (2) and 6.47 (15)° with their parent ring and are oriented at 11.2 (3)° with respect to each other. An intramolecular N—H⋯O hydrogen bond completes an S(6) ring motif. In the crystal, molecules are linked by C—H⋯O interactions, thus forming (010) chains in which R (2) (2)(13) ring motifs are present. There also exist aromatic π–π stacking interactions [centroid–centroid separation = 3.7046 (9) Å]. |
format | Text |
id | pubmed-3007257 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072572010-12-30 1-(2,4-Dinitrophenyl)-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazine Danish, M. Hamid, Masood Tahir, M. Nawaz Ahmad, Nazir Ghafoor, Sabiha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)N(4)O(4), the dihedral angle between the benzene rings is 10.42 (8)°. The nitro groups make dihedral angles of 5.3 (2) and 6.47 (15)° with their parent ring and are oriented at 11.2 (3)° with respect to each other. An intramolecular N—H⋯O hydrogen bond completes an S(6) ring motif. In the crystal, molecules are linked by C—H⋯O interactions, thus forming (010) chains in which R (2) (2)(13) ring motifs are present. There also exist aromatic π–π stacking interactions [centroid–centroid separation = 3.7046 (9) Å]. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007257/ /pubmed/21588393 http://dx.doi.org/10.1107/S1600536810028680 Text en © Danish et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Danish, M. Hamid, Masood Tahir, M. Nawaz Ahmad, Nazir Ghafoor, Sabiha 1-(2,4-Dinitrophenyl)-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazine |
title | 1-(2,4-Dinitrophenyl)-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazine |
title_full | 1-(2,4-Dinitrophenyl)-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazine |
title_fullStr | 1-(2,4-Dinitrophenyl)-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazine |
title_full_unstemmed | 1-(2,4-Dinitrophenyl)-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazine |
title_short | 1-(2,4-Dinitrophenyl)-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazine |
title_sort | 1-(2,4-dinitrophenyl)-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007257/ https://www.ncbi.nlm.nih.gov/pubmed/21588393 http://dx.doi.org/10.1107/S1600536810028680 |
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