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2-(4-Methyl­cyclo­hex-3-en­yl)propan-2-yl N-phenyl­carbamate

In the title carbamate compound, C(17)H(23)NO(2), one of the Csp (3) atoms of the cyclo­hexene ring is disordered over two sites with refined occupancies of 0.55 (2) and 0.45 (2), both disorder components resulting in half-boat conformations. The mean plane through the carbamate unit is inclined at...

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Autores principales: Ghalib, Raza Murad, Sulaiman, Othman, Mehdi, Sayed Hasan, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007260/
https://www.ncbi.nlm.nih.gov/pubmed/21588225
http://dx.doi.org/10.1107/S1600536810025080
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author Ghalib, Raza Murad
Sulaiman, Othman
Mehdi, Sayed Hasan
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Ghalib, Raza Murad
Sulaiman, Othman
Mehdi, Sayed Hasan
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Ghalib, Raza Murad
collection PubMed
description In the title carbamate compound, C(17)H(23)NO(2), one of the Csp (3) atoms of the cyclo­hexene ring is disordered over two sites with refined occupancies of 0.55 (2) and 0.45 (2), both disorder components resulting in half-boat conformations. The mean plane through the carbamate unit is inclined at inter­planar angles of 14.80 (13), 18.30 (17) and 24.0 (2)°, respectively, with respect to the phenyl ring, and the major and minor disorder component cyclo­hexene rings. In the crystal structure, adjacent mol­ecules are linked into chains along [001] via inter­molecular N—H⋯O hydrogen bonds. The crystal structure is further stabilized by weak inter­molecular C—H⋯π inter­actions.
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spelling pubmed-30072602010-12-30 2-(4-Methyl­cyclo­hex-3-en­yl)propan-2-yl N-phenyl­carbamate Ghalib, Raza Murad Sulaiman, Othman Mehdi, Sayed Hasan Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title carbamate compound, C(17)H(23)NO(2), one of the Csp (3) atoms of the cyclo­hexene ring is disordered over two sites with refined occupancies of 0.55 (2) and 0.45 (2), both disorder components resulting in half-boat conformations. The mean plane through the carbamate unit is inclined at inter­planar angles of 14.80 (13), 18.30 (17) and 24.0 (2)°, respectively, with respect to the phenyl ring, and the major and minor disorder component cyclo­hexene rings. In the crystal structure, adjacent mol­ecules are linked into chains along [001] via inter­molecular N—H⋯O hydrogen bonds. The crystal structure is further stabilized by weak inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007260/ /pubmed/21588225 http://dx.doi.org/10.1107/S1600536810025080 Text en © Ghalib et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ghalib, Raza Murad
Sulaiman, Othman
Mehdi, Sayed Hasan
Goh, Jia Hao
Fun, Hoong-Kun
2-(4-Methyl­cyclo­hex-3-en­yl)propan-2-yl N-phenyl­carbamate
title 2-(4-Methyl­cyclo­hex-3-en­yl)propan-2-yl N-phenyl­carbamate
title_full 2-(4-Methyl­cyclo­hex-3-en­yl)propan-2-yl N-phenyl­carbamate
title_fullStr 2-(4-Methyl­cyclo­hex-3-en­yl)propan-2-yl N-phenyl­carbamate
title_full_unstemmed 2-(4-Methyl­cyclo­hex-3-en­yl)propan-2-yl N-phenyl­carbamate
title_short 2-(4-Methyl­cyclo­hex-3-en­yl)propan-2-yl N-phenyl­carbamate
title_sort 2-(4-methyl­cyclo­hex-3-en­yl)propan-2-yl n-phenyl­carbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007260/
https://www.ncbi.nlm.nih.gov/pubmed/21588225
http://dx.doi.org/10.1107/S1600536810025080
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