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2-(4-Methylcyclohex-3-enyl)propan-2-yl N-phenylcarbamate
In the title carbamate compound, C(17)H(23)NO(2), one of the Csp (3) atoms of the cyclohexene ring is disordered over two sites with refined occupancies of 0.55 (2) and 0.45 (2), both disorder components resulting in half-boat conformations. The mean plane through the carbamate unit is inclined at...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007260/ https://www.ncbi.nlm.nih.gov/pubmed/21588225 http://dx.doi.org/10.1107/S1600536810025080 |
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author | Ghalib, Raza Murad Sulaiman, Othman Mehdi, Sayed Hasan Goh, Jia Hao Fun, Hoong-Kun |
author_facet | Ghalib, Raza Murad Sulaiman, Othman Mehdi, Sayed Hasan Goh, Jia Hao Fun, Hoong-Kun |
author_sort | Ghalib, Raza Murad |
collection | PubMed |
description | In the title carbamate compound, C(17)H(23)NO(2), one of the Csp (3) atoms of the cyclohexene ring is disordered over two sites with refined occupancies of 0.55 (2) and 0.45 (2), both disorder components resulting in half-boat conformations. The mean plane through the carbamate unit is inclined at interplanar angles of 14.80 (13), 18.30 (17) and 24.0 (2)°, respectively, with respect to the phenyl ring, and the major and minor disorder component cyclohexene rings. In the crystal structure, adjacent molecules are linked into chains along [001] via intermolecular N—H⋯O hydrogen bonds. The crystal structure is further stabilized by weak intermolecular C—H⋯π interactions. |
format | Text |
id | pubmed-3007260 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072602010-12-30 2-(4-Methylcyclohex-3-enyl)propan-2-yl N-phenylcarbamate Ghalib, Raza Murad Sulaiman, Othman Mehdi, Sayed Hasan Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title carbamate compound, C(17)H(23)NO(2), one of the Csp (3) atoms of the cyclohexene ring is disordered over two sites with refined occupancies of 0.55 (2) and 0.45 (2), both disorder components resulting in half-boat conformations. The mean plane through the carbamate unit is inclined at interplanar angles of 14.80 (13), 18.30 (17) and 24.0 (2)°, respectively, with respect to the phenyl ring, and the major and minor disorder component cyclohexene rings. In the crystal structure, adjacent molecules are linked into chains along [001] via intermolecular N—H⋯O hydrogen bonds. The crystal structure is further stabilized by weak intermolecular C—H⋯π interactions. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007260/ /pubmed/21588225 http://dx.doi.org/10.1107/S1600536810025080 Text en © Ghalib et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ghalib, Raza Murad Sulaiman, Othman Mehdi, Sayed Hasan Goh, Jia Hao Fun, Hoong-Kun 2-(4-Methylcyclohex-3-enyl)propan-2-yl N-phenylcarbamate |
title | 2-(4-Methylcyclohex-3-enyl)propan-2-yl N-phenylcarbamate |
title_full | 2-(4-Methylcyclohex-3-enyl)propan-2-yl N-phenylcarbamate |
title_fullStr | 2-(4-Methylcyclohex-3-enyl)propan-2-yl N-phenylcarbamate |
title_full_unstemmed | 2-(4-Methylcyclohex-3-enyl)propan-2-yl N-phenylcarbamate |
title_short | 2-(4-Methylcyclohex-3-enyl)propan-2-yl N-phenylcarbamate |
title_sort | 2-(4-methylcyclohex-3-enyl)propan-2-yl n-phenylcarbamate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007260/ https://www.ncbi.nlm.nih.gov/pubmed/21588225 http://dx.doi.org/10.1107/S1600536810025080 |
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