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Poly[dimethylammonium [aquadi-μ(2)-oxalato-dysprosate(III)] trihydrate]
The title compound, {(C(2)H(8)N)[Dy(C(2)O(4))(2)(H(2)O)]·3H(2)O}(n), was obtained as an unexpected product under hydrothermal conditions. The Dy(III) atom is chelated by four oxalate anions, two of which are situated on two different centres of inversion. The distorted tricapped trigonal-prismatic...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007264/ https://www.ncbi.nlm.nih.gov/pubmed/21588143 http://dx.doi.org/10.1107/S1600536810026140 |
Sumario: | The title compound, {(C(2)H(8)N)[Dy(C(2)O(4))(2)(H(2)O)]·3H(2)O}(n), was obtained as an unexpected product under hydrothermal conditions. The Dy(III) atom is chelated by four oxalate anions, two of which are situated on two different centres of inversion. The distorted tricapped trigonal-prismatic coordination sphere of the Dy(III) atom is completed by a water molecule. The bridging mode of the anions results in the formation of a three-dimensional network with cavities where the ammonium cations and the uncoordinated water molecules reside. The structure is stabilized by numerous N—H⋯O and O—H⋯O hydrogen-bonding interactions. |
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