Poly[dimethyl­ammonium [aquadi-μ(2)-oxalato-dysprosate(III)] trihydrate]

The title compound, {(C(2)H(8)N)[Dy(C(2)O(4))(2)(H(2)O)]·3H(2)O}(n), was obtained as an unexpected product under hydro­thermal conditions. The Dy(III) atom is chelated by four oxalate anions, two of which are situated on two different centres of inversion. The distorted tricapped trigonal-prismatic...

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Detalles Bibliográficos
Autores principales: Ye, Su-Fang, Lin, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007264/
https://www.ncbi.nlm.nih.gov/pubmed/21588143
http://dx.doi.org/10.1107/S1600536810026140
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author Ye, Su-Fang
Lin, Hong
author_facet Ye, Su-Fang
Lin, Hong
author_sort Ye, Su-Fang
collection PubMed
description The title compound, {(C(2)H(8)N)[Dy(C(2)O(4))(2)(H(2)O)]·3H(2)O}(n), was obtained as an unexpected product under hydro­thermal conditions. The Dy(III) atom is chelated by four oxalate anions, two of which are situated on two different centres of inversion. The distorted tricapped trigonal-prismatic coordination sphere of the Dy(III) atom is completed by a water mol­ecule. The bridging mode of the anions results in the formation of a three-dimensional network with cavities where the ammonium cations and the uncoordinated water mol­ecules reside. The structure is stabilized by numerous N—H⋯O and O—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-30072642010-12-30 Poly[dimethyl­ammonium [aquadi-μ(2)-oxalato-dysprosate(III)] trihydrate] Ye, Su-Fang Lin, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {(C(2)H(8)N)[Dy(C(2)O(4))(2)(H(2)O)]·3H(2)O}(n), was obtained as an unexpected product under hydro­thermal conditions. The Dy(III) atom is chelated by four oxalate anions, two of which are situated on two different centres of inversion. The distorted tricapped trigonal-prismatic coordination sphere of the Dy(III) atom is completed by a water mol­ecule. The bridging mode of the anions results in the formation of a three-dimensional network with cavities where the ammonium cations and the uncoordinated water mol­ecules reside. The structure is stabilized by numerous N—H⋯O and O—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007264/ /pubmed/21588143 http://dx.doi.org/10.1107/S1600536810026140 Text en © Ye and Lin 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ye, Su-Fang
Lin, Hong
Poly[dimethyl­ammonium [aquadi-μ(2)-oxalato-dysprosate(III)] trihydrate]
title Poly[dimethyl­ammonium [aquadi-μ(2)-oxalato-dysprosate(III)] trihydrate]
title_full Poly[dimethyl­ammonium [aquadi-μ(2)-oxalato-dysprosate(III)] trihydrate]
title_fullStr Poly[dimethyl­ammonium [aquadi-μ(2)-oxalato-dysprosate(III)] trihydrate]
title_full_unstemmed Poly[dimethyl­ammonium [aquadi-μ(2)-oxalato-dysprosate(III)] trihydrate]
title_short Poly[dimethyl­ammonium [aquadi-μ(2)-oxalato-dysprosate(III)] trihydrate]
title_sort poly[dimethyl­ammonium [aquadi-μ(2)-oxalato-dysprosate(iii)] trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007264/
https://www.ncbi.nlm.nih.gov/pubmed/21588143
http://dx.doi.org/10.1107/S1600536810026140
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