Dichlorido[tris­(benzimidazol-2-ylmeth­yl)amine]­indium(III) chloride ethanol solvate dihydrate

In the title complex, [InCl(2)(C(24)H(21)N(7))]Cl·C(2)H(5)OH·2H(2)O, the In(III) ion is coordinated by four N atoms from the tris­(benz­imidazol-2-ylmeth­yl)amine (NTB) ligand and two Cl atoms in a distorted octa­hedral environment. In the crystal structure, inter­molecular N—H⋯O, O—H⋯O, O—H⋯Cl and...

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Detalles Bibliográficos
Autores principales: Xiao, Zuo-an, Zhan, Dan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007265/
https://www.ncbi.nlm.nih.gov/pubmed/21588111
http://dx.doi.org/10.1107/S1600536810029806
Descripción
Sumario:In the title complex, [InCl(2)(C(24)H(21)N(7))]Cl·C(2)H(5)OH·2H(2)O, the In(III) ion is coordinated by four N atoms from the tris­(benz­imidazol-2-ylmeth­yl)amine (NTB) ligand and two Cl atoms in a distorted octa­hedral environment. In the crystal structure, inter­molecular N—H⋯O, O—H⋯O, O—H⋯Cl and weak C—H⋯Cl hydrogen bonds connect the cations, anions and solvent mol­ecules into a three-dimensional network. The ethanol solvent mol­ecule is disordered over two sites with refined occupancies of 0.54 (2) and 0.46 (2).

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