Dichlorido[tris­(benzimidazol-2-ylmeth­yl)amine]­indium(III) chloride ethanol solvate dihydrate

In the title complex, [InCl(2)(C(24)H(21)N(7))]Cl·C(2)H(5)OH·2H(2)O, the In(III) ion is coordinated by four N atoms from the tris­(benz­imidazol-2-ylmeth­yl)amine (NTB) ligand and two Cl atoms in a distorted octa­hedral environment. In the crystal structure, inter­molecular N—H⋯O, O—H⋯O, O—H⋯Cl and...

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Detalles Bibliográficos
Autores principales: Xiao, Zuo-an, Zhan, Dan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007265/
https://www.ncbi.nlm.nih.gov/pubmed/21588111
http://dx.doi.org/10.1107/S1600536810029806
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author Xiao, Zuo-an
Zhan, Dan
author_facet Xiao, Zuo-an
Zhan, Dan
author_sort Xiao, Zuo-an
collection PubMed
description In the title complex, [InCl(2)(C(24)H(21)N(7))]Cl·C(2)H(5)OH·2H(2)O, the In(III) ion is coordinated by four N atoms from the tris­(benz­imidazol-2-ylmeth­yl)amine (NTB) ligand and two Cl atoms in a distorted octa­hedral environment. In the crystal structure, inter­molecular N—H⋯O, O—H⋯O, O—H⋯Cl and weak C—H⋯Cl hydrogen bonds connect the cations, anions and solvent mol­ecules into a three-dimensional network. The ethanol solvent mol­ecule is disordered over two sites with refined occupancies of 0.54 (2) and 0.46 (2).
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spelling pubmed-30072652010-12-30 Dichlorido[tris­(benzimidazol-2-ylmeth­yl)amine]­indium(III) chloride ethanol solvate dihydrate Xiao, Zuo-an Zhan, Dan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [InCl(2)(C(24)H(21)N(7))]Cl·C(2)H(5)OH·2H(2)O, the In(III) ion is coordinated by four N atoms from the tris­(benz­imidazol-2-ylmeth­yl)amine (NTB) ligand and two Cl atoms in a distorted octa­hedral environment. In the crystal structure, inter­molecular N—H⋯O, O—H⋯O, O—H⋯Cl and weak C—H⋯Cl hydrogen bonds connect the cations, anions and solvent mol­ecules into a three-dimensional network. The ethanol solvent mol­ecule is disordered over two sites with refined occupancies of 0.54 (2) and 0.46 (2). International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007265/ /pubmed/21588111 http://dx.doi.org/10.1107/S1600536810029806 Text en © Xiao and Zhan 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xiao, Zuo-an
Zhan, Dan
Dichlorido[tris­(benzimidazol-2-ylmeth­yl)amine]­indium(III) chloride ethanol solvate dihydrate
title Dichlorido[tris­(benzimidazol-2-ylmeth­yl)amine]­indium(III) chloride ethanol solvate dihydrate
title_full Dichlorido[tris­(benzimidazol-2-ylmeth­yl)amine]­indium(III) chloride ethanol solvate dihydrate
title_fullStr Dichlorido[tris­(benzimidazol-2-ylmeth­yl)amine]­indium(III) chloride ethanol solvate dihydrate
title_full_unstemmed Dichlorido[tris­(benzimidazol-2-ylmeth­yl)amine]­indium(III) chloride ethanol solvate dihydrate
title_short Dichlorido[tris­(benzimidazol-2-ylmeth­yl)amine]­indium(III) chloride ethanol solvate dihydrate
title_sort dichlorido[tris­(benzimidazol-2-ylmeth­yl)amine]­indium(iii) chloride ethanol solvate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007265/
https://www.ncbi.nlm.nih.gov/pubmed/21588111
http://dx.doi.org/10.1107/S1600536810029806
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AT zhandan dichloridotrisbenzimidazol2ylmethylamineindiumiiichlorideethanolsolvatedihydrate

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