3β,11α-Dihy­droxy-17a-oxa-d-homoandrost-5-en-17-one

The title compound, C(19)H(28)O(4), was prepared from DHEA (dehydro­epiandrosterone) by its biotransformation using whole cells of the filamentous fungus Beauveria bassiana. The asymmetric unit contains two mol­ecules. The lactone ring is trans-positioned to the neighboring six-membered ring. In the...

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Detalles Bibliográficos
Autores principales: Świzdor, Alina, Białońska, Agata, Kołek, Teresa, Panek, Anna
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007275/
https://www.ncbi.nlm.nih.gov/pubmed/21588317
http://dx.doi.org/10.1107/S1600536810026516
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author Świzdor, Alina
Białońska, Agata
Kołek, Teresa
Panek, Anna
author_facet Świzdor, Alina
Białońska, Agata
Kołek, Teresa
Panek, Anna
author_sort Świzdor, Alina
collection PubMed
description The title compound, C(19)H(28)O(4), was prepared from DHEA (dehydro­epiandrosterone) by its biotransformation using whole cells of the filamentous fungus Beauveria bassiana. The asymmetric unit contains two mol­ecules. The lactone ring is trans-positioned to the neighboring six-membered ring. In the crystal structure, O—H⋯O hydrogen bonds form layers, which are linked to each other by O—H⋯O and C—H⋯O hydrogen bonds.
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spelling pubmed-30072752010-12-30 3β,11α-Dihy­droxy-17a-oxa-d-homoandrost-5-en-17-one Świzdor, Alina Białońska, Agata Kołek, Teresa Panek, Anna Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(28)O(4), was prepared from DHEA (dehydro­epiandrosterone) by its biotransformation using whole cells of the filamentous fungus Beauveria bassiana. The asymmetric unit contains two mol­ecules. The lactone ring is trans-positioned to the neighboring six-membered ring. In the crystal structure, O—H⋯O hydrogen bonds form layers, which are linked to each other by O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007275/ /pubmed/21588317 http://dx.doi.org/10.1107/S1600536810026516 Text en © Świzdor et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Świzdor, Alina
Białońska, Agata
Kołek, Teresa
Panek, Anna
3β,11α-Dihy­droxy-17a-oxa-d-homoandrost-5-en-17-one
title 3β,11α-Dihy­droxy-17a-oxa-d-homoandrost-5-en-17-one
title_full 3β,11α-Dihy­droxy-17a-oxa-d-homoandrost-5-en-17-one
title_fullStr 3β,11α-Dihy­droxy-17a-oxa-d-homoandrost-5-en-17-one
title_full_unstemmed 3β,11α-Dihy­droxy-17a-oxa-d-homoandrost-5-en-17-one
title_short 3β,11α-Dihy­droxy-17a-oxa-d-homoandrost-5-en-17-one
title_sort 3β,11α-dihy­droxy-17a-oxa-d-homoandrost-5-en-17-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007275/
https://www.ncbi.nlm.nih.gov/pubmed/21588317
http://dx.doi.org/10.1107/S1600536810026516
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AT panekanna 3b11adihydroxy17aoxadhomoandrost5en17one

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